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MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Consider the following processes: ∆H (kJ/mol) 1/2A → B +150 3B → 2C + D –125 E + A → 2D +350 For B + D → E + 2C, ∆H will be (Mains 2011)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The following data is known about the melting of a compound AB. ∆H = 9.2 kJ mol–1. ∆S = 0.008 kJ K–1mol–1. Its melting point is :

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. If the standard free energy difference is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamond a…

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which one of the following is not always negative?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

H and E  for the reaction, Fe O s 3H g 2Fe s H O l → at constant temperature are related as (a) H E (b) H E RT (c) H E RT (d) H E 3RT

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The enthalpy of vaporisation of a compound AB at its boiling point (127°C) is 6.4 kJ mol-1. Its entropy of vaporization is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the reaction, 2H O g 2H g O g → ∆H = 571.6 KJ fH of water is :

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

In a reaction P + Q → R + S, there is no change in entropy. Enthalpy change for the reaction (∆H) is 12 kJ mol–1. Under what conditions, reaction will have negative value of free energy change?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Enthalpy change for the reaction, 4H(g)  → 2H₂(g) is – 869.5 kJ. The dissociation energy of H–H bond is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

∆H for the reaction, SO g O g SO g ∆H = –98.3 kJ If the enthalpy of formation of SO₃(g) is –395.4 kJ then the enthalpy of formation of SO₂(g) is :

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following reactions define o f G ? (a) diamond C O g CO g → (b) H g F g HF g → (c) H P O H O 2H PO → (d) SO g O g SO g →

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A reaction occurs spontaneously if (2005)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The enthalpy of vaporisation of a substance is 8400 J mol–1 and its boiling point is –173ºC. The entropy change for vaporisationis :

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which one among the following is the correct option for right relationship between CP and CV for one mole of ideal gas? (NEET 2021)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A reaction having equal energies of activation for forward and reverse reactions has (NEET 2013)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the gas phase reaction, PCl g PCl g Cl g Which of the following conditions are correct?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which one of the following is correct? (a) G H T S

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

G is the net energy available to do useful work and is a measure of free energy. If a reaction has positive enthalpy change and positive entropy change, under what conditions will the reaction be spontaneous?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

It is impossible for a reaction to take place if (a) H is +ve and  S  is +ve (b) H is –ve and  S  is +ve (c) H is +ve and  S  is –ve (d) H is –ve and  S  is –ve

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A reaction has ∆H = – 33 kJ and ∆S = +58 J/K. This reaction would be :

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Pick out the wrong statement

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

2 moles of ideal gas at 27°C temperature is expanded reversibly from 2 lit. to 20 lit. find entropy change. (R = 2 cal/mol K)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The entropy change when two moles of ideal monoatomic gas is heated from 200°C to 300°C reversibly and isochorically?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

In which case change in entropy is negative?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

When one mole of an ideal gas is compressed to half of its initial volume and simultaneously heated to twice its initial temperature, the change in entropy of gas (∆S) is :

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