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19,000+ solved questions for JEE Advanced, JEE Mains, NEET & IChO — with answers and expert explanations.

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MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following processes is a non-spontaneous process?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The standard free energy change  G  is related to K (equilibrium constant) as

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The enthalpy of vaporisation of a substance is 8400 J mol–1 and its boiling point is –173ºC. The entropy change for vaporisationis :

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

In an adiabatic expansion of ideal gas

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

When ice melts into water, entropy

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The absolute enthalpy of neutralisation of the reaction: (g) (g) 2(aq) (l) MgO 2HCl MgCl H O → Will be (2005)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Entropy is a measure of

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following statements is not correct?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Given that bond energies of H – H and Cl – Cl are 430 kJ mol–1 and 240 kJ mol–1 respectively and f H for HCl is-90 kJ mol–1 bond enthalpy of HCl is (2007)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which law states that entropy of all pure crystalline solids is zero at absolute zero?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Thermodynamically, the most stable form of carbon

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For a reaction: X → Y + Z absolute entropies are X = 120 JK–1 mol–1 Y = 213.8 JK–1 mol–1 and Z = 197.9 JK–1 mol–1. What will be the entropy change at 298 K and 1 atm?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Entropy of the universe is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which one of the following is not always negative?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The correct thermodynamic conditions for the spontaneous reaction at all temperatures is (NEET-I 2016)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The standard enthalpies of formation of HCl(g), H  (g) and  Cl₂(g)  are  –92.2,  217.7  and  121.4  kJ  mol-1 respectively. The bond dissociation energy of HCl is:

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The molar heat capacity of water at constant pressure, C, is 75J K-1. When 1.0 kJ of heat is supplied to 100 g of water which is free to expand, the increase in temperature of water is. (2003)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the reaction, 8 g 2 g 2 g l C H 5O 3CO 4H O → at constant temperature, H E is (2003)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following processes is irreversible?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

When 0.5 g of sulphur is burnt to SO₂ 4.6 kJ of heat is liberated. What is the enthalpy of formation of sulphurdioxide?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The heat of formation of Fe O s is –824.2 kJ mol–1. ∆H for the reaction. 2Fe O s 4Fe s 3O g → is:

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Internal energy is the sum of

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

In an isothermal expansion of an ideal gas

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

105. (∆U – ∆H) for the formation of NH₃ from N₂ and H₂ is :

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Regarding the internal energy of the molecule, which of the following statement is correct?

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