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MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following statements is not correct?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The standard free energy change  G  is related to K (equilibrium constant) as

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Entropy is a measure of

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which law states that entropy of all pure crystalline solids is zero at absolute zero?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

2 moles of ideal gas at 27°C temperature is expanded reversibly from 2 lit. to 20 lit. find entropy change. (R = 2 cal/mol K)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Identify the correct statement regarding entropy.

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Thermodynamically, the most stable form of carbon

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

In an adiabatic expansion of ideal gas

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

In thermodynamics a process is called reversible when

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The statement “The change of enthalpy of a chemical reaction is same whether the reaction takes place in one or several steps” is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

When ice melts into water, entropy

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A system absorbs 10 kJ of heat and does 4 kJ of work. The internal energy of the system

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

In an isothermal expansion of an ideal gas

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following processes is reversible?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Internal energy is the sum of

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following processes is irreversible?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Entropy of the universe is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Tea placed in thermos flask is an example of

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A thermally isolated gaseous system can exchange energy with the surroundings. The mode of energy may be

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which is included in thermodynamic equilibrium from the following?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

In which of the following cases, the reaction is spontaneous at all temperatures ?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

G is the net energy available to do useful work and is a measure of free energy. If a reaction has positive enthalpy change and positive entropy change, under what conditions will the reaction be spontaneous?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Regarding the internal energy of the molecule, which of the following statement is correct?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following processes is a non-spontaneous process?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For a reaction: X → Y + Z absolute entropies are X = 120 JK–1 mol–1 Y = 213.8 JK–1 mol–1 and Z = 197.9 JK–1 mol–1. What will be the entropy change at 298 K and 1 atm?

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