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19,000+ solved questions for JEE Advanced, JEE Mains, NEET & IChO — with answers and expert explanations.

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MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the gas phase reaction, 5(g) 3(g) 2(g) PCl PCl Cl Which of the following conditions are correct? (2008)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

From the following bond energies: H — H bond energy : 431.37 kJ mol–1 C == C bond energy : 606.10 kJ mol–1 C — C bond energy : 336.49 kJ mol–1 C — H bond energy : 410.50 kJ mol–1 Enthalpy for the reaction, will be (2009)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following are not state functins? (I) q + w (II) Q (III) w (IV) H – TS (2009)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Given that bond energies of H – H and Cl – Cl are 430 kJ mol–1 and 240 kJ mol–1 respectively and f H for HCl is-90 kJ mol–1 bond enthalpy of HCl is (2007)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Enthalpy change for the reaction, 4H(g) 2H (g) → is – 869.6 kJ. The dissociation energy of H–H bond is (CBSE AIPMT 2011)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following is a state function and also an extensive property?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Identify the correct statement regarding entropy.

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Tea placed in thermos flask is an example of

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assume each reaction is carried out in an open container. For which reaction will H = E ? (CBSE AIPMT 2006) (a) H (g) Br (g) 2HBr(g) → (b) C(s) 2H O(g) 2H (g) CO (g) → (c) PCl (g) PCl (g) Cl (g) → (d) 2CO(g) O (g) 2CO…

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A reaction occurs spontaneously if (2005)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Identify the correct statement for change of Gibbs’ energy for a system system ( G ) at constant temperature and pressure. (2006)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. The standard free energy difference ( G ) is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamon…

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The absolute enthalpy of neutralisation of the reaction: (g) (g) 2(aq) (l) MgO 2HCl MgCl H O → Will be (2005)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The enthalpy and entropy change for the reaction: 2(l) 2(g) (g) Br Cl 2BrCl → are 30 kJ mol–1 and 105JK–1 mol–1 respectively. The temperature at which the reaction will be in equilibrium is (2006)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following is a state variable?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Consider the following reaction –1 (aq) (aq) (l) –1 2(g) 2(g) (l) 2(g) 2(g) (g) (l) –1 2(g) 2(g) 2(g) (l) –1 (i)H OH H O , H X kJ mol (ii)H 1/ 2O H O , H X kJ mol (iii)CO H CO H O , H X kJ mol (iv)C H 5 / 2O 2CO H O ,…

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The molar heat capacity of water at constant pressure, C, is 75J K-1. When 1.0 kJ of heat is supplied to 100 g of water which is free to expand, the increase in temperature of water is. (2003)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

If the enthalpy change for the transition of liquid water to steam is 30 kJ mol–1 at 27°C, the entropy change for the process would be (2011)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

If the bond energies of H–H, Br–Br, and H–Br are 433, 192 and 364 kJ mol–1 respectively, the H for the reaction 2(g) 2(g) (g) H Br 2HBr → is (2004)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following is a path function?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following is not an intensive property?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A thermally isolated gaseous system can exchange energy with the surroundings. The mode of energy may be

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following is not a state function?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following quantities is not a state function?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following is not a state function?

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