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HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

B. P G T 2. T C. P H S 3. -S D. H T P 4. P 5. V

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Which of the following are extensive properties?

HARDINTEGERIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

If one monoatomic gas is expanded adiabatically from 2L to 10L at 1 atm external pressure then the value of U (in atm L) is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For which of the following cases H S T ?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Assertion: For an isolated system, q is zero. Reason: In an isolated system, change in U and V is zero.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Which of the following is intensive property?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

A system undergoes a 2-step process. In step 1, 15 J of work is done on the system as its internal energy increases by a total of 30 J. In step 2, at constant volume, the system decreases its internal energy by 20 J. …

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

A diatomic gas at pressure P, compressed adiabatically to half of its volume, what is the final pressure?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

When 1 mol of an ideal gas is compressed to half of its volume, its temperature becomes double; then the change in entropy (S) would be:

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

In an isobaric process, when temperature changes from 1T to T , S is equal to

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Assertion: There is no change in internal energy for an ideal gas at constant temperature. Reason: Internal energy of an ideal gas is a function of temperature only.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Assertion: In isothermal process, whole of heat energy supplied to the system is converted into internal energy. Reason: According to the first law of thermodynamics U = q - w

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Assertion: Addition of Q and w gives ΔU. Reason: Addition of two path functions cannot give state function.

HARDINTEGERIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The heat liberated when 1.89g of benzoic acid is burnt in a bomb calorimeter at 25 °C and it increases the temperature of 18.94 kg of water by 0.632 °C. if the specific heat of water at 25 °C is 0.998 cal/g- °C, the v…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Which thermodynamic parameter is not a state function?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

A system undergoes a 3-step process. In step 1, 25 J of work is done by the system as its internal energy (U) decreases by 50 J. In step 2, w = -15J and q = +40J. In step 3 at constant volume, the system gives off 50 …

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

1 mole of an ideal gas expands isothermally reversibly from 2 litre to 4 litre and 3 moles of the same gas expands from 2 litre to x litre and doing same work, what is ‘x’?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

A liquid which is confined inside an adiabatic piston is suddenly taken from state 1 to state 2 by a single stage process. If the piston comes to rest at point 2 as shown. Then the enthalpy change for the process will…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The magnitudes of enthalpy changes for irreversible adiabatic expansion of a gas from 1L to 2L is H₁ and for reversible adiabatic expansion for the same expansion is H₂. Then

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For the reaction of one mole of zinc dust with one mole of sulphuric acid in a bomb calorimeter, U and w correspond to

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Consider the reaction below at 298 K: C (graphite) + 2H₂ (g) → CH₄ (g) →fHº (kJ/mol) – 74.9 S₀ m(J/K/mol + 5.6 + 130.7 Which statement below is correct ?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

What is the entropy change in 2 mol N₂, when its temperature is taken from 400 K to 800 K. at constant pressure?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Bond dissociation energy of CH₄ is 360 kJ/mol and C₂H₆ is 620 kJ/mol. Then bond dissociation energy of C – C bond is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Assertion: The extensive properties of a single pure substance will not only depend upon the number of moles of the substance present but also on any two of the three variables. Reason: Any extensive property if expre…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Match List I with List II and select the correct answer using the codes given below the lists: List – I List – II A. T G P

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