Chemistry Question Bank

For the reaction, A B + C, at equilibrium, the concentration of A is 1 × 10–3 M, B is 0.15 and C is 0.05 M. The Gº for the hydrolysis of A at 27ºC will be :

The free energy of formation of NO is 78 kJ mol–1 at the temperature of an automobile engine (1000 K). What is the equilibrium constant for this reaction at 1000 K ? N (g) O (g) NO(g)

In each of the following, total pressure set-up at equilibrium is assumed to be equal and is one atm with equilibrium constants KP given : I :CaCO3 (s) CaO (s) + CO2 (g), K1 II : NH4HS (s) NH3 (g) + H2S (g), K2 III :…

For a reversible reaction : A + B C dx dt = 2.0 × 103 L mol–1 s–1 [A] [B] – 1.0 × 102 s–1 [C] where x is the amount of ‘A’ dissociated. The value of equilibrium constant (Keq) is :

The standard state Gibb’s free energy change for the isomerization reaction cis-2-pentene trans-2-pentene is –3.67 kJ mol–1 at 400 K. If more trans-2-pentene is added to the reaction vessel

Consider the reaction PCl5 (g) PCl3 (g) + Cl2 (g) in a closed container at equilibrium. At a fixed temperature what will be the effect of adding more PCl5 on the equilibrium concentration of Cl2 (g) ?

The effect of increasing the pressure on the equilibrium 2A(g) + 3B(g) 3A(g) + 2B(g) is

Following gaseous reaction is undergoing in a vessel C2H4 + H2 C2H6; H = – 32.7 Kcal Which will increase the equilibrium concentration of C2H6

In the reaction A(g) + 2B(g) C(g) + Q kJ, greater product will be obtained or the forward reaction is favoured by

According to Le-Chatelier principle, if heat is given to solid-liquid system, then

The reaction A + B C + D +heat has reached equilibrium. The reaction may be made to proceed forward by

In the following reversible reaction 2SO2 + O2 2SO3 + Q Cal Most suitable condition for the higher production of SO3 is

Which of the following reactions proceed at low pressure

N2 + O2 2NO - Q cals In the above reaction which is the essential condition for the higher production of NO

The formation of SO3 takes place according to the following reaction, 2SO2 + O2 2SO3 ; H = – 45.2 Kcal The formation of SO3 is favoured by

In the reaction, A2(g) + 4 B2(g) 2AB4(g) + heat the formation of AB4will be favoured at

Which of the following statements regarding a chemical equilibrium is wrong

In equilibrium CH3COOH + H2O CH3COO– + H The equilibrium constant may change when

1.1 mole of A is mixed with 2.2 mole of B and the mixture is kept in a one-litre flask till the equilibrium, A + 2B 2C + D is reached. At equilibrium 0.2 mol of C is formed. The equilibrium constant of the above react…

4 moles of A are mixed with 4 moles of B when 2 moles of C are formed at equilibrium according to the reaction A + B C + D The value of the equilibrium constant is

One mole of SO3 was placed in a vessel of 1 litre capacity at a certain temperature when the following equilibrium was established 2 SO3 2 SO2 + O2 At equilibrium, 0.6 moles of SO2 were formed. The equilibrium consta…

56 g of N2 and 6g H2 were kept at 400ºC in l litre vessel. The equilibrium mixture contained 27.54g of NH3. The approximate value of Kc for the above reaction in mol-2 lit2 is

Two moles of HI were heated in a sealed tube at 440ºC till the equilibrium was reached. HI was found to be 22% decomposed. The equilibrium constant for dissociation is

The decomposition of N2O4 to NO2 is carried out at 280º C in chloroform. When equilibrium is reached 0.2 mol of N2O4 and 2 × 10–3mol of NO2 are present in 2 litre solution. The equilibrium constant for the reaction N2…

For the system A (g) + 2 B (g) C (g) the equilibrium concentrations are A = 0.06 mol L–1 B = 0.12 mol L–1 C = 0.216 mol L–1. The Keq for the reaction is