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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

H O l H O vap. In this equation, the double half arrows indicate that

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

The equilibrium constant in a reversible chemical reaction at a given temperature

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

The rate constant for forward and backward reactions of hydrolysis of ester are 1.1 × 10–2 and 1.5 × 10–3 per minute respectively. Equilibrium constant for the reaction is CH3COOC2H5 + H2O CH3COOH + C2H5OH

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

The solid-vapour equilibrium can be represented as I. I2 (solid) I2 (vapour) II. Camphor (solid) Camphor (vapour) III. NH4Cl (solid) NH4Cl (vapour) Point out the correct option(s).

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Which of the following statement is correct?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

For any pure liquid at 1 atm pressure (1.013 bar), the temperature at which the liquid and vapours are at equilibrium is called normal …(X)… of the liquid. Here, (X) refers to

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

H O l H O vap. Point out the correct statement for this equilibrium

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

For any pure substance at atmospheric pressure, the temperature at which the solid and liquid phases are at equilibrium is called the normal …(X)… or normal …(Y)… of the substance.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Ice and water kept in a perfectly insulated thermos flask (no exchange of heat between its contents and the surroundings) at 273 K and the atmospheric pressure are in equilibrium state and the system shows

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Solid Liquid Liquid Gas Solid Gas The above examples are called

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Which of the following is correct for equilibrium state?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Equilibria involving O2 molecules and the protein heamoglobin play a crucial role

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Chemical equilibria are important in numerous … (X) … and …. (Y) … processes. Here, (X) and (Y) refer to

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Equilibrium constant K1 and K2 for the following equilibria (AIPMT 2005) K NO(g) O NO (g) K 2NO (g) 2NO(g) O (g) are related as (a) K K (b) K K (c) K K (d) K K Ans. (d) Sol. Reaction (2) is a reverse reactio…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Assertion : For a reaction at equilibrium, the free energy for the reaction is minimum. Reason : The free energy for both reactants and products decreases and become equal.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

In a 1.0 L aqueous solution when the reaction (aq) (s) 2 Ag Cu (aq) (s) Cu 2 Ag reaches equilibrium, [Cu2+] = x M and [Ag+] = y M. If the volume of solution is doubled by adding water, then at equilibrium : (a) x …

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Variation of log K with 1 T is shown by the following graph. Hº for the reaction will be :

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

In each of the following, total pressure set-up at equilibrium is assumed to be equal and is one atm with equilibrium constants KP given : I :CaCO3 (s) CaO (s) + CO2 (g), K1 II : NH4HS (s) NH3 (g) + H2S (g), K2 III :…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

For the chemical equilibrium, CaCO (s) CaO(s) CO (g) , Hº can be determined from which one of the following graphs ? (a) (b) (c) (d)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

If for the heterogeneous equilibrium CaCO3(s) CaO(s) + CO2 (g) ; K = 1 at 1 atm, the temperature is given by : (a) Sº T Hº (b) Hº T Sº (c) Gº T R (d) Gº T Hº

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Hydrolysis of sucrose is given by the following reaction : Sucrose H O Glucose Fructose If the equilibrium constant (KC) is 2 10 x at 300 K, the value of o rG at the same temperature will be (NEET 2020) (a) 8.3…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Which one of the following conditions will favour maximum formation of the product in the reaction, A2 (g) + B2 (g) X2 (g); rH = – X kJ? (NEET 2018)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

A 20 litre container at 400 K contains CO2(g) at pressure 0.4 atm and an excess of SrO (neglect the volume of solid SrO). The volume of the container is now decreased by moving the movable piston fitted in the contain…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

The equilibrium constants of the following are N 3H 2NH ;K N O 2NO;K H O H O;K The equilibrium constant (K) of the reaction : K 2NH O 2NO 3H O will be (NEET 2017) (a) K K K (b) K K K (c) K K K (d) K K K

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Which of the following statements is correct for a reversible process in a state of equilibrium? (NEET 2015) (a) o G 2.30RT log K (b) o G 2.30 RT log K

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