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H O l H O vap. In this equation, the double half arrows indicate that
The equilibrium constant in a reversible chemical reaction at a given temperature
The rate constant for forward and backward reactions of hydrolysis of ester are 1.1 × 10–2 and 1.5 × 10–3 per minute respectively. Equilibrium constant for the reaction is CH3COOC2H5 + H2O CH3COOH + C2H5OH
The solid-vapour equilibrium can be represented as I. I2 (solid) I2 (vapour) II. Camphor (solid) Camphor (vapour) III. NH4Cl (solid) NH4Cl (vapour) Point out the correct option(s).
Which of the following statement is correct?
For any pure liquid at 1 atm pressure (1.013 bar), the temperature at which the liquid and vapours are at equilibrium is called normal …(X)… of the liquid. Here, (X) refers to
H O l H O vap. Point out the correct statement for this equilibrium
For any pure substance at atmospheric pressure, the temperature at which the solid and liquid phases are at equilibrium is called the normal …(X)… or normal …(Y)… of the substance.
Ice and water kept in a perfectly insulated thermos flask (no exchange of heat between its contents and the surroundings) at 273 K and the atmospheric pressure are in equilibrium state and the system shows
Solid Liquid Liquid Gas Solid Gas The above examples are called
Which of the following is correct for equilibrium state?
Equilibria involving O2 molecules and the protein heamoglobin play a crucial role
Chemical equilibria are important in numerous … (X) … and …. (Y) … processes. Here, (X) and (Y) refer to
Equilibrium constant K1 and K2 for the following equilibria (AIPMT 2005) K NO(g) O NO (g) K 2NO (g) 2NO(g) O (g) are related as (a) K K (b) K K (c) K K (d) K K Ans. (d) Sol. Reaction (2) is a reverse reactio…
Assertion : For a reaction at equilibrium, the free energy for the reaction is minimum. Reason : The free energy for both reactants and products decreases and become equal.
In a 1.0 L aqueous solution when the reaction (aq) (s) 2 Ag Cu (aq) (s) Cu 2 Ag reaches equilibrium, [Cu2+] = x M and [Ag+] = y M. If the volume of solution is doubled by adding water, then at equilibrium : (a) x …
Variation of log K with 1 T is shown by the following graph. Hº for the reaction will be :
In each of the following, total pressure set-up at equilibrium is assumed to be equal and is one atm with equilibrium constants KP given : I :CaCO3 (s) CaO (s) + CO2 (g), K1 II : NH4HS (s) NH3 (g) + H2S (g), K2 III :…
For the chemical equilibrium, CaCO (s) CaO(s) CO (g) , Hº can be determined from which one of the following graphs ? (a) (b) (c) (d)
If for the heterogeneous equilibrium CaCO3(s) CaO(s) + CO2 (g) ; K = 1 at 1 atm, the temperature is given by : (a) Sº T Hº (b) Hº T Sº (c) Gº T R (d) Gº T Hº
Hydrolysis of sucrose is given by the following reaction : Sucrose H O Glucose Fructose If the equilibrium constant (KC) is 2 10 x at 300 K, the value of o rG at the same temperature will be (NEET 2020) (a) 8.3…
Which one of the following conditions will favour maximum formation of the product in the reaction, A2 (g) + B2 (g) X2 (g); rH = – X kJ? (NEET 2018)
A 20 litre container at 400 K contains CO2(g) at pressure 0.4 atm and an excess of SrO (neglect the volume of solid SrO). The volume of the container is now decreased by moving the movable piston fitted in the contain…
The equilibrium constants of the following are N 3H 2NH ;K N O 2NO;K H O H O;K The equilibrium constant (K) of the reaction : K 2NH O 2NO 3H O will be (NEET 2017) (a) K K K (b) K K K (c) K K K (d) K K K
Which of the following statements is correct for a reversible process in a state of equilibrium? (NEET 2015) (a) o G 2.30RT log K (b) o G 2.30 RT log K