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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The decomposition of N2O5 in CCl4 at 318 K has been studied by monitoring the concentration of N2O5 in the solution. Initially the concentration of N2O5 is 1.16 mol L-1 and after 92 min, it is reduced to 1.04 mol L-1.…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In the reaction given below 2HI g H g I g -> hoose the correct alternative.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The square brackets in the expression Δ[R] = [R]2 – [R]1 are used to express …A… Here, A is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Speed of a reaction can be defined as

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The units of rate of reaction are

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Rate of a reaction

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate of reaction is defined as

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a reaction R ⟶ P, the concentration of a reactant changes from 0.05 M to 0.04 M in 30 minutes. What will be the average rate of reaction in minutes?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the reaction A + 2B ⟶ C, the rate of reaction at a given instant can be represented by (a) d[A] 1 d[B] d[C] dt 2 dt dt

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the reaction. 2 HI ⟶ H2 + I2, the expression [ ] d HI dt represents

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In a reaction 2HI ⟶ H2 + I2, the concentration of HI decreases from 0.5 mol L–1 to 0.4 mol L–1 in 10 minutes. What is the overall rate of reaction during this interval?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Consider the reaction, 2N O 4NO O . -> In the reaction NO2 is being formed at the rate of 0.0125 mol L–1 s–1. What is the rate of reaction at this time?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

The reaction between N2 and H2 to form ammonia has Kc = 6 × 10–2 at the temperature 500°C. The numerical value of Kp for this reaction is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

For the reaction : N (g) O (g) NO(g) If pressure is increased by reducing the volume of the container, then

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Au(s) Au(l) Above equilibrium is favoured at

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

When a gas “X” is dissolved in water, the heat is evolved. Then solubility of ‘X’ will increase at

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

If for a particular reversible reaction : Kc = 57 at 355ºC and Kc = 69 at 450º, then

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

For exothermic reaction is Sº < 0, then the sketch of log K vs 1/T may be (a) (b) (c) (d)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

If standard heat of dissociation of PCl5 is 230 cal, then slope of the graph of log k vs 1 T is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Assertion : For PCl5(g) PCl3(g) + Cl2(g). If more Cl2 is added, the equilibrium will shift in backward direction hence equilibrium constant will decrease. Reason : Addition of inert gas to the equilibrium mixture at…

HARDINTEGERIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Assertion :A catalyst does not influence the value of equilibrium constant. Reason : Catalyst influence the rate of both forward and backward reactions equally.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Assertion : The addition of an inert gas under constant volume condition cause the total pressure of the system to increase. This would thus lower the degree of dissociation of PCl5. Reason : Addition of inert gas at …

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Assertion : Addition of an inert gas at constant pressure equilibrium will support the dissociation of PCl5 at the same temperature. Reason : The addition of an inert gas will tend to increase the total pressure.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Assertion : For the reaction g g g g A B C D at the given temperature, there will be no effect by addition of inert gas either at constant pressure or at constant volume. Reason : For the reaction where n = 0,…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical Equilibrium

Assertion : Kp is equal to Kc for the following reaction: N2(g) + O2(g) 2NO(g) Reason : Kp and Kc are interrelated by the following equation : g n p c K K (RT) ng = Number of gaseous moles of products – Number of g…

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