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MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

The  hydrogen  ion  concentration  of  a 10M  HCl aqueous solution at 298 K  w K 10 is (AIPMT 2006)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

At  25oC  the dissociation  constant  of  a base,  BOH,  is 1.0×10–12. The concentration of hydroxyl ions in 0.01 M  aqueous  solution  of  the  base  would  be  (AIPMT 2005)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

If 0.1 M of a weak acid is taken and its percentage of degree  of  ionization  is  1.34%,  then  its  ionization constant will be (AFMC 2005)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Neutralization of an acid with a base, invariably results in the production of

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

At  18ºC,  the  solubility  product  of  AgCl  is 1.8  ×  10–10.  In  the  solution,  the  value  of  [Ag+]  is 4  ×  10–3mol/litre.  The  value  of  [Cl–]  to  precipitate AgCl from this solution should be greater than

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

The concentration of Ag+ ion in a given saturated solution of AgCl at 25ºC is 1.06 × 10–5g ion per litre. Thus the solubility product of AgCl is

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

The solubility product of a sparingly soluble salt AB at room temperature is 1.21 × 10–6 M2. Its molar solubility is

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

If the maximum concentration of PbCl2 in water is 0.01 M at 25ºC, its maximum concentration in 0.1 M NaCl will be

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

What is the value of Ksp for PbCl2 ?

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Assertion: When aqueous, solution of CH3COONH4 is diluted, then its degree of hydrolysis increases. Reason:  Ammonium  acetate  is  the  salt  of  weak  acid and  weak  base;  its  degree  of  hydrolysis  does  not de…

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Assertion: Aqueous  solution of  ammonium  carbonate is basic. Reason: Acidic or Basic nature of a salt solution of a salt  of  weak  acid  and  weak  base  depends  on  Ka  and Kb of the acid and base forming it.

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Assertion: If a K  of HA is 10–3 and a K  of HB is 10 at 25ºC, pH of an aqueous solution of HB will be one unit greater than pH of equimolar solution of HA. Reason:  For  weak  acids,  both  concentration  and ionizat…

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

When one drop of a concentrated HCl is added to 1 L of pure water at 25ºC, the pH drops suddenly from 7 to 4. When the second drop of the same acid is added, the pH of the solution further drops to about

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

The pH of 10–5 M HCl solution if 1 ml of it is diluted to 1000 ml is :

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

A buffer is prepared by adding 0.30 mol CH3COONa to 2.0  L  of  a  0.10  M  CH3COOH  solution.  Calculate the eq K /c (x y) eq K c/(xy) 1/(x y) x y 1 x y eq K /c x y eq K /xyc pH  after  0.030  mol  HCl  are …

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Which  pair  of  reagents,  mixed  in  the  appropriate proportion, could make a buffer in pH 3-4 range ?

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Assertion: If HA and HB are two weak non-basic acids with Ka(HA)  < Kb(HB), then, the aqueous solution  of NaA will have higher pH than pH of aqueous solution of NaB of same concentration. Reason: Conjugate base of  a…

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The values of dissociation constants of some acids (at 25°C)  are  as  follows.  Indicate  which  is  the  strongest acid in water

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

0.2 molar solution  of formic acid is ionized  3.2%.  Its ionization constant is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Degree  of  dissociation  of  0.1  N  CH3COOH  is (Dissociation constant = 1 × 10 –5)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The  degree  of  dissociation  of  0.1  M  HCN  solution is 0.01%. Its ionisation constant would be

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The  following  equilibrium  exists  in  aqueous  solution, CH3COOH   CH3COO – + H + if dil. HCl is added, without change in temperature, the

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

A monoprotic acid in 1.00 M solution is 0.01% ionised. The dissociation constant of this acid is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Which of the following is the weakest acid?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Which  equilibrium  can  be  described  as  an  acid-base reaction using the Lewis’s acid-base definition, but not using Bronsted-Lowry definition ?

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