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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Which  of  the  following  fluoro-compounds  is  most likely to behave as a Lewis’s base?  (NEET-II 2016)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The  percentage  of  pyridine (C H N)   that  forms pyridinium  ion (C H N H) in  a  0.10  M  aqueous pyridine solution ( b K  for C H N 1.7 10 ) x is (NEET 2016)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

What  is  the  pH  of  the  resulting  solution  when  equal volumes of 0.1 M NaOH  and 0.01  M HCl are mixed  ? (AIPMT 2015)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

At 100C the Kw of water is 55 times its value at 25C. What will be the pH of neutral solution? (log 55 = 1.74) (NEET 2013)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Accumulation  of  lactic  acid  (HC3H5O3),  a  monobasic acid in tissues leads to pain and a feeling of fatigue. In a 0.10  M  aqueous  solution,  lactic  acid  is  3.7% dissociated. The value of dissociation constant…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Identify  the  correct  order  of  solubility  in  aqueous medium. (NEET 2013)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The values of Ksp of CaCO3 and CaC2O4 are 4.7 x 10-9 and 1.3 x 10-9  respectively at  25C. If the mixture of these  two  is  washed  with  water,  what  is  the concentration of Ca2+ ions in water? (NEET 2013)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The dissociation constant of a weak acid is 1 x 104. In order to  prepare  a  buffer  solution with  a  pH  =  5,  the [Salt]/[Acid] ratio should be (NEET 2013)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Which of these is least likely to act as a Lewis’s acid? (NEET 2013)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Buffer  solutions  have  constant  acidity  and  alkalinity because (AIPMT 2012)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Equimolar  solutions  of  the  following  substances  were prepared separately. Which one of these will record the highest pH value? (AIPMT 2012)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

pH of a saturated solution of Ba(OH)2 is 12. The value of solubility product (Ksp) of Ba(OH)2 is (AIPMT 2012, 2010)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

A buffer solution is prepared in which the concentration of NH3 is 0.30 M and the concentration of NH is 0.20 M. If the equilibrium constant, Kb for NH3 equal 1.8 x 105, what is the pH of this solution? (log 2.7 = 0.4…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Which  of  the  following  is  least  likely  to  behave  as Lewis’s base? (AIPMT 2011)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Aqueous solution of acetic acid contains

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The  solubility  of  CaCO3  is  7  mg/L.  Calculate  the solubility product of BaCO3 from this information and from  the  fact that  when  Na2CO3  is added slowly  to  a solution  containing  equimolar  concentration …

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The solubility of AgCl is maximum in

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The solubility of LiOH in a solution with pH = 8 is (Ksp = 1.8 × 10–12)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Assertion (A): pH of HCl solution is less than that of acetic acid of the same concentration. Reason (R):  In  equimolar  solutions,  the  number  of titrable protons present in HCl in less than that present in acetic…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Assertion: If HA and HB are two weak non-basic acids with Ka(HA)  < Kb(HB), then, the aqueous solution  of NaA will have higher pH than pH of aqueous solution of NaB of same concentration. Reason: Conjugate base of  a…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The solubility product of Ag2CrO4 is 32 × 10–12. What is  the  concentration  of  ions  in  that  solution (in g ions L–1)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The least soluble compound (salt) of the following is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The Ksp of CuS, Ag2S and HgS are 10–31, 10–44 and 10–54 respectively. The solubility of these sulphides are in the order

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Why only As+3 gets precipitated as As2S3 and not Zn+2 as ZnS when H2S is passed through an acidic solution containing As+3 and Zn+2 ?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The pH of an aqueous solution of Ba(OH)2 is 10. If the Ksp of Ba(OH)2 is 1 × 10–9, then the concentration of Ba2+ ions in the solution in mol L–1 is

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