MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibriumPrevious Year Questions

Which  of  the  following  is  least  likely  to  behave  as Lewis’s base? (AIPMT 2011)

A.OH–
B.H2O
C.NH3
D.BF3✓ Correct
Explanation

3 BF   is 2 sp   hybridized  with  trigonal planar structure. The central atom present in these have incomplete octet due  to  shortage  of  electrons.  It  can  accept  electrons from  any  Lewis’s  base  and  can  act  as  Lewis’s  acid. Therefore, it is least likely to behave as base.

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