MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibriumPrevious Year Questions

At 100C the Kw of water is 55 times its value at 25C. What will be the pH of neutral solution? (log 55 = 1.74) (NEET 2013)

A.7.00
B.7.87
C.5.13✓ Correct
D.6.13
Explanation

We know that, at 25C, Kw = 1x1014 At 100C, Kw = 55 x 1016 - w K H OH IONIC EQUILIBRIUM 57 2 14 14 14 H H 55 10 pH log H pH log 55 10 1 1 log 55 10 log55 14log10 2 2 1 1 1.74 14 12.26 6.13 2 2 w K >> x x x 33. Which  of  the  following  salts  will  give  highest  pH  in water? (AIPMT 2014) (a) KCl (b) NaCl (c) 2 3 Na CO (d) 4 CuSO The  reaction  with  water  of  given  compounds  is  as follows: 2 3 2 2 3 2 2 4 2 2 4 2 Na CO + H NaOH +H CO NaCl+H O NaOH +HCl KCl+H O KO

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