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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

An ideal gas expands isothermally from 10–3 m3 to 10–2 m3 at 300 K against a constant pressure of 105 N m–2. The work done on the gas is (Odisha NEET 2019)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For the reaction, 2Cl(g) → Cl₂(g), the correct option is (NEET 2020)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The bond dissociation energies of X2, Y₂ and XY are in the ratio of 1 : 0.5 : 1. ∆H for the formation of XY is – 200 kJ mol–1. The bond dissociation energy of X2 will be (NEET 2018)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For a given reaction, ∆H = 35.5 kJ mol–1 and ∆S = 83.6 J K–1 mol–1. The reaction is spontaneous at (Assume that ∆H and ∆S do not vary with temperature.) (NEET 2017)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Under isothermal conditions, a gas at 300 K expands from 0.1 L to 0.25 L against a constant external pressure of 2 bar. The work done by the gas is [Given that 1 L bar = 100 J] (NEET 2019)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The entropy change when two moles of ideal monoatomic gas is heated from 200°C to 300°C reversibly and isochorically?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

When one mole of an ideal gas is compressed to half of its initial volume and simultaneously heated to twice its initial temperature, the change in entropy of gas (∆S) is :

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Which thermodynamic parameter is not a state function?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For a sample of perfect gas when its pressure is changed isothermally from pi to pf, the entropy change is given by. (NEET-II 2016)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The heat of combustion of carbon to CO₂ is –393.5 kJ/mol. The heat released upon formation of 35.2 g of CO₂ from carbon and oxygen gas is (2015)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Consider the following liquid-vapour equilibrium. Liquid ⇌ Vapour Which of the following relations is correct? (NEET-I 2016) (a) v H dln P dT T (b) v H d ln P dT RT (c) v H dln G dT RT (d) v H d ln P dT RT

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Enthalpy change for the reaction, 4H(g)  → 2H₂(g) is – 869.5 kJ. The dissociation energy of H–H bond is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

In a reaction, all reactant and products are liquid, then (a) H E (b) H E (c) H E

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For the reaction, X2O₄(l) → 2XO₂(g) ∆U = 2.1 kcal, ∆S = 20 cal K–1 at 300 K Hence, ∆G is (2014)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

A gas is allowed to expand in a well-insulated container against a constant external pressure of 2.5 atm from an initial volume of 2.50 L to a final volume of 4.50 L. The change in internal energy U of the gas in joul…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The enthalpy of vaporisation of a compound AB at its boiling point (127°C) is 6.4 kJ mol-1. Its entropy of vaporization is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For the reaction, 2H O g 2H g O g → ∆H = 571.6 KJ fH of water is :

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

H and E  for the reaction, Fe O s 3H g 2Fe s H O l → at constant temperature are related as (a) H E (b) H E RT (c) H E RT (d) H E 3RT

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Which of the following reactions define o f G ? (a) diamond C O g CO g → (b) H g F g HF g → (c) H P O H O 2H PO → (d) SO g O g SO g →

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

A system undergoes a 3-step process. In step 1, 25 J of work is done by the system as its internal energy (U) decreases by 50 J. In step 2, w = -15J and q = +40J. In step 3 at constant volume, the system gives off 50 …

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Assertion: There is no change in internal energy for an ideal gas at constant temperature. Reason: Internal energy of an ideal gas is a function of temperature only.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The following data is known about the melting of a compound AB. ∆H = 9.2 kJ mol–1. ∆S = 0.008 kJ K–1mol–1. Its melting point is :

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The state of a thermodynamic system is represented by

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

105. (∆U – ∆H) for the formation of NH₃ from N₂ and H₂ is :

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Entropy of the universe is

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