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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

A given mass of gas expands from state A to state B by three paths 1, 2, and 3 as shown in the figure: If w ,w  and w  respectively, be the work done by the gas along three paths, then (a) w w w (b) w w w

HARDINTEGERIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The heat liberated when 1.89g of benzoic acid is burnt in a bomb calorimeter at 25 °C and it increases the temperature of 18.94 kg of water by 0.632 °C. if the specific heat of water at 25 °C is 0.998 cal/g- °C, the v…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

A reaction having equal energies of activation for forward and reverse reactions has (NEET 2013)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Equal volumes of two monatomic gases, A and B at same temperature and pressure are mixed. The ratio of specific heats (CP/CV) of the mixture will be (2012)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The correct thermodynamic conditions for the spontaneous reaction at all temperatures is (NEET-I 2016)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

16g of oxygen gas expands isothermally and reversibly at 300 K from 10 dm3 to 100 dm3. The work done is (in J)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Read the following statements regarding spontaneity of a process and mark the appropriate choice. (i)   When enthalpy factor is absent then randomness factor decides spontaneity of a process. (ii) When randomness fact…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

If the bond energies of H–H, Br–Br, and H–Br are 433, 192 and 364 kJ mol–1 respectively, the H for the reaction 2(g) 2(g) (g) H Br 2HBr → is (2004)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Which of the following p-V curve represents maximum work done? (NEET 2022) (a) (b) (c) (d) Ans. (b) Sol. Option (b), represents maximum work done

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

G H when S

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For the reaction, X2O₄(l) → 2XO₂(g) ∆U = 2.1 kcal, ∆S = 20 cal K–1 at 300 K Hence, ∆G is (2014)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Tea placed in thermos flask is an example of

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Gaseous system is placed with pressure P₁, volume V₁ and  temperature  T1,  it  has  undergone  thermodynamic changes where temperature is remaining constant, it is

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Based on the first law of thermodynamics, which one of the following is correct?

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

In ….. process, work is done at the expense of internal energy.

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Find rH at 320 K for the reaction is:

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: Entropy of system increases for a spontaneous reaction. Reason: Enthalpy of reaction always not decreases for spontaneous reaction.

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Find r S at 320 K for the reaction is:

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: For an isolated system, q is zero. Reason: In an isolated system, change in U and V is zero.

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: In isothermal process, whole of heat energy supplied to the system is converted into internal energy. Reason: According to the first law of thermodynamics U = q - w

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: Addition of Q and w gives ΔU. Reason: Addition of two path functions cannot give state function.

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: A reaction which is spontaneous and accompanied by decrease of randomness must be exothermic. Reason: All exothermic reactions are accompanied by decrease in randomness.

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

U q w , is mathematical expression for

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

In an isobaric process, when temperature changes from 1T to T , S is equal to

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

B. P G T 2. T C. P H S 3. -S D. H T P 4. P 5. V

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