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MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

Table sugar is a

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

The commonest disaccharide has the molecular formula

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

Which of the following is a non-reducing sugar?

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryBiomolecules

What is the structure of L-Glucose? (a) (b) (c)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Assertion: SN2 reaction of CH3––Br is faster in Cl CH S – SCH3 Cl (CH ) CHS 3 2 – SCH(CH ) 3 2 DMSO than in H2O. Reason: DMSO has greater capability to solvate nucleophile.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Which of the following has the highest normal boiling point?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Assertion: Chloral reacts with phenyl chloride to form DDT. Reason: It is an electrophilic substitution reaction

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Assertion: A dichlorobenzene is slightly more reactive than chlorobenzene towards an aromatic nucleophilic substitution reaction. Reason: Chlorine has electron withdrawing effect on aromatic ring.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Assertion: p-nitrochlorobenzene is more reactive than m-nitrochlorobenzene towards aromatic nucleophilic substitution reaction. Reason: Nitro group from para and meta positions has opposite effect in aromatic nucleoph…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Assertion: The reaction of bulky base such as potassium tertiary butoxide [(CH3)3CO–K+] with secondary alkyl halides gives predominantly E2 elimination product rather than SN2 substitution product. Reason: The transit…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Assertion: Ph–CO–CH2CH2OCH3 has greater reactivity for E1CB than for E2 reaction. Reason: A poor leaving group and acidic —H favour E1CB mechanism.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Assertion: Treatment of either enantiomer of 2-chlorobutane with ethanolic KOH results in trans-2- butene as major elimination product. Reason: Elimination with ethanolic KOH is a bimolecular reaction.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Assertion: Chlorination of allylic hydrogen is difficult than vinylic hydrogen. Reason: Allyl radical is stabilised by resonance.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Assertion (A): The boiling points of alkyl halides decreases in the order RI > RBr > RCl > RF Reason (R): The boiling points of alkyl chlorides, bromides and iodides are considerably higher than that of the hydrocarb…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

A bromoalkane ‘X’ reacts with magnesium in dry ether to form compound ‘Y’. The reaction of ‘Y’ with methanol followed by hydrolysis yield an alcohol having molecular formula, C4H10O. The compound ‘X’ is (AIIMS 2018)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Hydrocarbon (A) reacts with bromine by substitution to form an alkyl bromide which by Wurtz reaction is converted to gaseous hydrocarbon containing less than four carbon atoms. A is (NEET 2018) (a) CH…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Among the following, the suitable reagent for Wurtz reaction is (JIPMER 2018)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

CH OH/H (i) CO Mg/ether (ii)H O CH Br P ->->-> Which is the product ‘P’ in the above reaction? (JIPMER 2018)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Identify the major product that is obtained on treatment of CH CH CH F CH with CH O / CH OH is (JIPMER 2018) (a) CH CH CH OCH CH (b) CH CH CHCH (c) CH CH CH CH (d) CH CH CH CH OCH SOLID STATE

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Neopentyl chloride reacts with benzene in presence of a Lewis acid (AlCl3) to form (JIPMER 2018) (a) (b) (c) (d)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Identify A and predict the type of reaction. (NEET 2017) (a) and elimination addition reaction (b) and cine substitution reaction. (c) and cine substitution. (d) and substitution reaction.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

For the following reactions, (i) CH CH CH Br KOH CH CH CH KBr H O -> (ii) (iii) Which of the following statements is correct? (NEET 2016)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

Consider the reaction, CH CH CH Br NaCN CH CH CH CN NaBr -> This reaction will be the fastest in (NEET 2016)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

The reaction of C6H5CH=CHCH3 with HBr produces (AIPMT 2015)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl Halides

In an SN1 reaction on chiral centres, there is (AIPMT 2015)

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