Chemistry Question Bank

Of the following which change will shift the reaction towards the product? (AIIMS 2004) o r I g 2I g , H 298K 150kJ

The reaction (g) (g) (g) N O 2NO is endothermic. The forward reaction is (BHU 2003)

The reaction quotient (Q) for the reaction N (g) 3H (g) 2NH (g) is given by [NH ] Q . [N ][H ] (CBSE Med. 2003) The reaction will proceed from right to left if

Densities of diamond and graphite are 3.5 and 2.3 g/mL respectively. Increase of pressure on the equilibrium C (diamond) C (graphite)

In the equilibrium reaction AgCl(s) + 2NH3(g) 3 2 Ag(NH ) (aq) Cl (aq), an increase in the concentration of Cl –(aq) causes

The volume of the reaction vessel containing an equilibrium mixture is increased, while holding the temperature constant for the following reaction : SO2Cl2(g) SO2(g) + Cl2(g) When equilibrium is re-established, which…

For the reaction, A B + C, at equilibrium, the concentration of A is 1 × 10–3 M, B is 0.15 and C is 0.05 M. The Gº for the hydrolysis of A at 27ºC will be :

The free energy of formation of NO is 78 kJ mol–1 at the temperature of an automobile engine (1000 K). What is the equilibrium constant for this reaction at 1000 K ? N (g) O (g) NO(g)

A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. Some of the CO2 is converted to CO on addition of graphite. If the total pressure at equilibrium is 0.8 atm, the value of K is :

For a reversible reaction : A + B C dx dt = 2.0 × 103 L mol–1 s–1 [A] [B] – 1.0 × 102 s–1 [C] where x is the amount of ‘A’ dissociated. The value of equilibrium constant (Keq) is :

The standard state Gibb’s free energy change for the isomerization reaction cis-2-pentene trans-2-pentene is –3.67 kJ mol–1 at 400 K. If more trans-2-pentene is added to the reaction vessel

Consider the reaction PCl5 (g) PCl3 (g) + Cl2 (g) in a closed container at equilibrium. At a fixed temperature what will be the effect of adding more PCl5 on the equilibrium concentration of Cl2 (g) ?

In which of the following system, doubling the volume of the container cause a shift to the right

The exothermic formation of ClF3 is represented by the equation Cl2(g) + 3F2(g) 2ClF3(g); H = – 329 kJ Which of the following will increase the quantity of ClF3 in an equilibrium mixture of Cl2, F2 and ClF3

The effect of increasing the pressure on the equilibrium 2A(g) + 3B(g) 3A(g) + 2B(g) is

Following gaseous reaction is undergoing in a vessel C2H4 + H2 C2H6; H = – 32.7 Kcal Which will increase the equilibrium concentration of C2H6

In the reaction A(g) + 2B(g) C(g) + Q kJ, greater product will be obtained or the forward reaction is favoured by

Which of the following statements regarding a chemical equilibrium is wrong

In equilibrium CH3COOH + H2O CH3COO– + H The equilibrium constant may change when

What is the effect of halving the pressure by doubling the volume on the following system at 500°C H2(g) + I2(g) 2HI(g)

In which of the following reaction Kp > Kc

The reaction between N2 and H2 to form ammonia has Kc = 6 × 10–2 at the temperature 500°C. The numerical value of Kp for this reaction is

For the reaction H2(g) + I2(g) 2HI(g) at 721K the value of equilibrium constant (Kc) is 50. When the equilibrium concentration of both is 0.5M, the value of Kp under the same conditions will be

In which of the following equilibria, the value of Kp is less than Kc

For N2(g) + 3H2(g) 2NH3(g) + heat