Chemistry Question Bank

Assertion : For a reaction at equilibrium, the free energy for the reaction is minimum. Reason : The free energy for both reactants and products decreases and become equal.

In a 1.0 L aqueous solution when the reaction (aq) (s) 2 Ag Cu (aq) (s) Cu 2 Ag reaches equilibrium, [Cu2+] = x M and [Ag+] = y M. If the volume of solution is doubled by adding water, then at equilibrium : (a) x …

Variation of log K with 1 T is shown by the following graph. Hº for the reaction will be :

In each of the following, total pressure set-up at equilibrium is assumed to be equal and is one atm with equilibrium constants KP given : I :CaCO3 (s) CaO (s) + CO2 (g), K1 II : NH4HS (s) NH3 (g) + H2S (g), K2 III :…

For the chemical equilibrium, CaCO (s) CaO(s) CO (g) , Hº can be determined from which one of the following graphs ? (a) (b) (c) (d)

If for the heterogeneous equilibrium CaCO3(s) CaO(s) + CO2 (g) ; K = 1 at 1 atm, the temperature is given by : (a) Sº T Hº (b) Hº T Sº (c) Gº T R (d) Gº T Hº

In reversible reaction k k A B , the initial concentration of A and B are a and b in moles per litre and the equilibrium concentration are (a – x) and (b + x) respectively ; express x in terms of k1, k2, a and b. (a…

For the all gas reaction at 1000 K : 2HI H2 + I2, K = 0.0344. If you were to begin with 8.0 M of HI in a fixed volume container, what would be the equilibrium concentration of H2 ?

Consider the reaction NaBr(aq) + H2SO4(aq) NaHSO4(aq) + HBr(aq). The equilibrium constant is 8.3 × 10 –2. If the equilibrium concentrations of NaBr, H2SO4 and NaHSO4 are 6.0 M, 9.0 M and 3.0 M respectively, what is th…

When A2 and B2 are allowed to react, the equilibrium constant of the reaction at 27ºC is found (Kc = 4). A2(g) + B2(g) 2AB(g) What will be the equilibrium concentration of AB ?

I I I This reaction is set-up in aqueous medium. We start with 1 mol of I2 and 0.5 mol of I– in 1L flask. After equilibrium is reached, excess of AgNO3 gave 0.25 mol of yellow ppt. Equilibrium constant is : [Given…

A 20 litre container at 400 K contains CO2(g) at pressure 0.4 atm and an excess of SrO (neglect the volume of solid SrO). The volume of the container is now decreased by moving the movable piston fitted in the contain…

The equilibrium constants of the following are N 3H 2NH ;K N O 2NO;K H O H O;K The equilibrium constant (K) of the reaction : K 2NH O 2NO 3H O will be (NEET 2017) (a) K K K (b) K K K (c) K K K (d) K K K

Which of the following statements is correct for a reversible process in a state of equilibrium? (NEET 2015) (a) o G 2.30RT log K (b) o G 2.30 RT log K

If the value of equilibrium constant for a particular reaction is 1.6 10 x , then at equilibrium the system will contain (NEET 2015)

If the equilibrium constant for 2 g 2 g g N O 2NO is K, the equilibrium constant for 2 g 2 g g N O NO will be (NEET 2015)

Consider the following gaseous equilibria with equilibrium constants K1 and K2 respectively. SO g O g SO g (KCET 2011) 2SO g 2SO g O g The equilibrium constants are related as (a) 2K K (b) K K (c) K K (d)…

For the reaction, N (g) O (g) 2NO(g) , the equilibrium constant is K1. The equilibrium constant is K2 for the reaction, 2NO(g) O (g) 2NO (g) . What is K for the reaction NO (g) N (g) O (g) (AIPMT 2011) (a) (K…

What is c K for the following equilibrium when equilibrium concentration of each substance is [SO ] 0.60 M, [O ] 0.82 M and [SO ] 1.90 M ? (VMMC 2010) 2SO (g) O (g) 2SO (g)

In which one of the following gaseous equilibria, p K is less than c K ? (CMC LUDHIYANA 2010) (a) N O 2NO (b) 2SO O 2SO (c) 2HI H I (d) N O 2NO

The relation between p c K and K for the following reaction is (JCECE 2010) N (g) 3H (g) 2NH (g) -> (a) p c K K (RT) (b) c p K K (RT) (c) c p K K (RT) (d) p c K K (RT)

At 450 K, p K 2.0 / bar x for the given reaction at equilibrium 2SO (g) O (g) 2SO (g) (HARYANA PMT 2010) What is c K at this temperature ? (a) 73.8 x (b) 7.38 10 x

In which of the following equilibrium Kc and Kp are not equal? (AIPMT 2010) (a) 2C s O g 2CO g (b) 2NO g N g O g p K (c) SO g NO g SO g NO g (d) H g I g 2HI g

For the reaction, AB g A g B g AB is 33% dissociated at a total pressure of p. Therefore, p is related to by one of the following options (AMU 2010)

Assertion For the reaction, 2NO g O g 2NO Increase in pressure favours the formation of NO2. Reason The reaction is exothermic (AIIMS 2009)