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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The unit of the rate constant of nth order is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The equilibrium constant of reaction is 20.0 At equilibrium, the rate constant of forward reaction is 10.0. The rate constant for backward reaction is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The unit of rate constant for a zero-order reaction is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate law for a reaction between the substances P and Q is given by rate a b k P Q On doubling the concentration of P and reducing the concentration of Q to one-half, the ratio of the new rate to the earlier rate…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Statement I The rate law may not depend on the concentration of every reactants. Statements II With increase in temperature, the rate of reaction increases. Choose the correct option regarding above statements.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The conversion of molecules x to y follows second order kinetics. If concentration of x is increased to three times how will it affect the rate of formation of y ?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Which of the following statement(s) is/are true? I.Rate law is an experimental fact while law of mass action is a theoretical proposal. II.Rate law is more informative than law of mass action for the development mecha…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the reaction A + B ⟶ C + D, doubling the concentration of both the reactants increases the reaction rate by 8 times and doubling the initial concentration of only B simply doubles the reaction rate. The rate law f…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In the reaction 2 A + B ⟶ Products, the order w.r.t. A is found to be one and w.r.t. B equal to 2. Concentration of A is doubled and that of B is halved, the rate of reaction will be

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the gaseous reaction 2A + B ⟶ C + D, the rate is given by k [A] [B]. The volume of the container containing the reaction mixture is suddenly reduced to one fourth of its original volume. with respect to the origin…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Consider the following statements regarding the equation given below, Hg l Cl g HgCl s -> I.Stoichiometric coefficients of the reactants and products are same in the above reaction. II.Rate of reaction Hg Cl…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the reaction R P, -> the concentration of a reactant changes from 0.03 M to 0.02 M in 25 min. Calculate the average rate of reaction using units of time in seconds.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In a reaction, 2A ->products, the concentration of A decreases from 1.0 mol L-1 to 0.8 mol L-1 in 20 min. Calculate the rate during this interval.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Assertion (A) Δ[R] is multiplied with -1 to make the rate of the reaction a positive quantity. Reason (R) Δ[R] is a negative quantity in the expression rate of disappearance of R R t

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Rate of a reaction can be expressed as I. The rate of decrease in concentration of any one of the reactants. II. The rate of increase in concentration of any one of the products. Which of the above mentioned statement…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate of formation of ammonia by the reaction : N2 + 3 H2 ⟶ 2 NH3 is expressed as d[NH ] dt = 2.5 × 10–4 mol L–1 s–1 . The rate of consumption of H2 expressed as d[H ] dt will be

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the reaction 4NH 5O 4NO 6H O, -> if the rate of disappearance of NH3 is 3.6 × 10–3 mol L-1 s–1, what is the rate of formation of H2O?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Similarly, the stoichiometric coefficient of D, A and B is 3,4 and 1 respectively. Thus using the concept, B D A C -> So, answer b is correct.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate of a reaction is expressed in different ways as follows : 1 d[C] 1 d[D] 1 d[A] d[B]. 2 dt 3 dt 4 dt dt The reaction is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a hypothetical reaction, R -> products; rate k R . The negative sign used in the rate expression indicates

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Choose the correct value of d NH dt for the reaction, N 3H 2NH -> (a) d H dt (b) d H dt (c) d N dt (d) d N dt Ans. (a) Sol. d NH d H dt dt

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In order to express the rate at a particular moment of time we determine the …A… rate. Here A refers to

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

When the concentrations of gases is expressed in terms of their partial pressures, then the units of the rate of reaction will be

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Find the value of from the graph shown below (a) av R r f (b) av R R r t t (c) av d R r dt (d) av R R r t t Ans. (d) Sol. av R R r t t

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In the graph, slope is (a) inst d R r dt (b) inst d R r d P (c) inst d P r dt (d) inst d P r dt Ans. (c) Sol. Slope ⇒ inst d P r dt

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