Chemistry Question Bank

For a certain reaction A -> products, the t1/2 as a function of [A]0 is given as below: [A]0 (M) : 0.1 0.025 t1/2 (min) : 100 Which of the following is/are true ?

The reaction of hydrogen and iodine monochloride is given as: H g 2ICl g 2HCl g I g -> The reaction is of first order with respect to H2 (g) and ICl(g), following mechanisms were proposed. Mechanism A: H g 2…

The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume. 2(g) 2(g) 2(g) SO Cl SO Cl -> Experimen t Time/s-1 Total pressure/atm 0.5 0.6 What is the rate of reaction…

Hydrolysis of methyl acetate in aqueous solution has been studied by titrating the liberated acetic acid against sodium hydroxide. The concentration of the ester at different times is given below. t/min C/mol L-1 0.85…

Half-lives of a first order and a zero order reaction are same. Then the ratio of the initial rates of first order reaction to that of the zero order reaction is (a) 0.693

T50 of first -order reaction is 10 min. Starting with 10 mol L–1, rate after 20 min is

A reaction which is of first order w.r.t. reactant A, has a rate constant 6 min–1. If we start with [A] = 0.5 mol L–1, when would [A] reach the value of 0.05 mol L–1

The rate constant for a first order reaction is 4.606 10 s x . The time required to reduce 2.0 g of the reactant to 0.2 g is: (NEET 2020)

The half-life for a zero order reaction having 0.02 M intial concetration of reactant is 100 s. The rate constant (in mol L-1 s-1) for the reaction (NEET 2020) (a) 1.0 10 x (b) 2.0 10 x (c) 2.0 10 x (d) 1.0 10 x

If the rate constant for a first order reaction is k, the time (t) required for the completion of 99% of the reaction is given by: (NEET 2019)

For the chemical reaction: (NEET 2019) N g H g NH g The correct option is: (a) d N d NH dt dt (b) d N d NH dt dt (c) d H d NH dt dt (d) d H d NH dt dt

A first order reaction has a rate constant of 2.303 × 10– 3 s–1. The time required for 40 g of this reactant to reduce to 10 g will be: [Given that log10 2 = 0.3010 (Odisha NEET 2019)

For a reaction, activation energy Ea = 0 and the rate constant at 200 K is 1.6 × 106 s–1. The rate constant at 400 K will be: [Given that gas constant R=8.314 J K–1 mol–1] (Odisha NEET 2019)

Formula for half-life of a zero order reaction is (JIPMER 2019) (a) C k (b) C 2k (c) 2C k (d) 2C 2k

If half-life of a substance is 36 minutes. Find amount left after 2 hrs. Initial amount is 10 g. (JIPMER 2019)

Find out time period of Ist order reaction when reaction complete 2/3rd, if the value of rate constant is 4.3 10 s x (JIPMER 2019) (a) 0.0025 10 sec x (b) 0.25 10 sec x (c) 0.025 10 sec x (d) 2.5 10 sec x

The correct difference between first and second order reactions is that (NEET 2018)

When initial concentration of the reactant is doubled, the half-life period of a zero order reaction (NEET 2018)

Mechanism of a hypothetical reaction X Y XY -> is given below: (i) fast X X X (ii) slow -> X Y XY Y (iii) fast X Y XY -> The overall order of the reaction will be; (NEET 2017)

A first order reaction has a specific reaction rate of 10– 2 sec–1. How much time will it take for 20g of the reactant to reduce to 5 g? (NEET 2017)

A first order reaction is 50% completed in 1.26 10 x s. How much time would it take for 100% completion? (JIPMER 2017) (a) 1.26 10 s x (b) 2.52 10 s x (c) 2.52 10 s x

The rate law for the reaction, xA yB mP nQ -> is rate = . c d k A B What is the total order of the reaction? (Kerala CEE 2011)

The rate of the reaction g g g NO Cl NOCl is given by the rate equation rate = k [NO]2 [Cl2]. The value of the rate constant can be increased by: (AIPMT 2010)

During the kinetic study of the reaction, 2A B C D -> , following results were obtained: Run [A]/mol L–1 [B]/mol L–1 Initial rate of formation of D/mol L–1 min–1 I 0.1 0.1 6.0 10 x II 0.3 0.2 7.2 10 x III 0.3 0.4 2.…

For an endothermic reaction, energy of activation is Ea and enthalpy of reaction of H (both of these in kJ/mol). Minimum value of Ea will be. (AIPMT 2010)