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During the kinetic study of the reaction, 2A B C D -> , following results were obtained: Run [A]/mol L–1 [B]/mol L–1 Initial rate of formation of D/mol L–1 min–1 I 0.1 0.1 6.0 10 x II 0.3 0.2 7.2 10 x III 0.3 0.4 2.…
For an endothermic reaction, energy of activation is Ea and enthalpy of reaction of H (both of these in kJ/mol). Minimum value of Ea will be. (AIPMT 2010)
For the reaction, N2 + 3H2 -> 2NH3, d NH dt = 2 x 10–4 mol L–1 s–1, the value of d H dt would be: (AIPMT 2009)
In the reaction -> aq aq l l BrO Br H Br H O The rate of appearance of bromine (Br2) is related to rate of disappearance of bromide ions as following: (AIPMT 2009)
Half life period of a first-order reaction is 1386 seconds. The specific rate constant of the reaction is: (AIPMT 2009) (a) 0.5 10 s x (b) 0.5 10 s x (c) 5.0 10 s x (d) 5.0 10 s x
rate = k [A]1 [B]2
For the reaction A + B -> products, it is observed that: (1) On doubling the initial concentration of A only, the rate of reaction is also doubled and (2) On doubling the initial concentrations of both A and B, there …
The bromination of acetone that occurs in acid solution is represented by this equation. CH COCH aq Br aq CH COCH Br aq H aq Br aq -> These kinetic data were obtained for given reaction concentrations. …
What will happen, on increasing the temperature or decreasing the activation energy (answer on the basis of Arrhenius equation)?
For the reaction A + 2B ⟶ C, the rate of reaction at a given instant can be represented by (a) d[A] 1 d[B] d[C] dt 2 dt dt
In the Arrhenius equation, a E /RT k Ae , the factor a E /RT e corresponds to the
On the basis of Arrhenius equation mentioned in Above ques. consider the following statements. I.Ea is activation energy. II.Unit of Ea is J mol-1 III.R is gas constant. Which of these are true statements?
In Arrhenius equation mentioned in Above Ques. ‘A’ is
The correct form of Arrhenius equation is (a) a E /RT k Ae (b) a RT/E k Ae (c) a E /RT k Ae (d) a RT/E k Ae
For the chemical reaction: (NEET 2019) N g H g NH g The correct option is: (a) d N d NH dt dt (b) d N d NH dt dt (c) d H d NH dt dt (d) d H d NH dt dt
Assertion (A): The order of a reaction can have fractional value. Reason (R): The order of a reaction cannot be written from balanced equation of a reaction.
Assertion (A): In rate law, unlike in the expression for equilibrium constants, the exponents for concentrations do not necessarily match the stoichiometric coefficients. Reason (R): It is the mechanism and not the ba…
Choose the correct answer out of the following choices. Assertion (A): Most people think diamond is forever. Reason (R): Conversion rate of diamond to graphite is very low.
Collision theory is used to explain how chemical species undergo a reaction. Using this theory and the kinetic molecular model, which of the following does NOT influence the rate of a chemical reaction?
For a first order reaction A P, the temperature (T) dependent rate constant (k) was found to follow the equation 1 logk 6.0 T . The pre- exponential factor A and the activation energy Ea, respectively are: (a) 1.0…
An endothermic reaction with high activation energy for the forward reaction is given by the diagram : (a) (b) (c) E E (d)
The potential energy diagram for a reaction R P -> is given below o H of the reaction corresponds to the energy:
Ea and H values of reactions R1, R2, R3 and R4 carried out at the same temperature are as given below: R1 Ea = 40 kJ mol–1, H = – 80 kJ mol–1 R2 Ea = 20 kJ mol–1, H = – 30 kJ mol–1 R3 Ea = 60 kJ mol–1, H = + 40 kJ mol…
The first order rate constant for a certain reaction increases from 1.667 × 10–6 s–1 at 727ºC to1.667 × 10–4 s–1 at 1571ºC. The rate constant at 1150ºC, assuming constancy of activation energy over the given temperatu…
In most cases, for a rise of 10K temperature the rate constant is doubled to tripled. This is due to the reason that (a)collision frequency increases by a factor of 2 to 3. (b)fraction of molecules possessing threshol…