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19,000+ solved questions for JEE Advanced, JEE Mains, NEET & IChO — with answers and expert explanations.

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HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Find rH at 320 K for the reaction is:

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Find r S at 320 K for the reaction is:

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Match List I with List II and select the correct answer using the codes given below the lists: List – I List – II A. T G P

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: A process is called adiabatic if the system does not exchange heat with the surroundings. Reason: It does not involve increase or decrease in temperature of the system

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: Entropy is always constant for a closed system. Reason: Closed system is always reversible.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: In isothermal process, whole of heat energy supplied to the system is converted into internal energy. Reason: According to the first law of thermodynamics U = q - w

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The heat of formation of Fe O s is –824.2 kJ mol–1. ∆H for the reaction. 2Fe O s 4Fe s 3O g → is:

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: For an isolated system, q is zero. Reason: In an isolated system, change in U and V is zero.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: Addition of Q and w gives ΔU. Reason: Addition of two path functions cannot give state function.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

One mole of an ideal diatomic gas (Cv = 5 cal) was transformed from initial 25°C and 1 L to the state when temperature is 100°C and volume 10 L. The entropy change of the process can be expressed as (R = 2 calories/mo…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: A reaction which is spontaneous and accompanied by decrease of randomness must be exothermic. Reason: All exothermic reactions are accompanied by decrease in randomness.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following is intensive property?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following processes is a non-spontaneous process?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which one among the following is the correct option for right relationship between CP and CV for one mole of ideal gas? (NEET 2021)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For irreversible expansion of an ideal gas under isothermal condition, the correct option is (NEET 2021)

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assertion: Entropy of system increases for a spontaneous reaction. Reason: Enthalpy of reaction always not decreases for spontaneous reaction.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Two moles of Helium gas undergo a reversible cyclic process as shown in figure. Assuming gas to be ideal. What is the work done for the process C to D?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following p-V curve represents maximum work done? (NEET 2022) (a) (b) (c) (d) Ans. (b) Sol. Option (b), represents maximum work done

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the reaction, 8 g 2 g 2 g l C H 5O 3CO 4H O → at constant temperature, H E is (2003)

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following are extensive properties?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. The standard free energy difference ( G ) is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamon…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A reaction occurs spontaneously if (2005)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assume each reaction is carried out in an open container. For which reaction will H = E ? (CBSE AIPMT 2006) (a) H (g) Br (g) 2HBr(g) → (b) C(s) 2H O(g) 2H (g) CO (g) → (c) PCl (g) PCl (g) Cl (g) → (d) 2CO(g) O (g) 2CO…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

If boiling point of water is 1000C. How much gram of NaCl is added in 500 g of water to increase its boiling point by approx o b H O 1 C K 0.52K kg / mole. x (AllMS 2019)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The mixture which shows positive deviation from Raoult’s law is: (NEET 2020)

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