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HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryElectrochemistry

A 1.0 M with respect to each of the metal halide AX3, BX2 CX3 and DX2 is electrolysed using platinum electrodes. If The correct sequence in which the various metals are deposited at the cathode is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryElectrochemistry

Assertion: Zinc can be used while copper cannot be used in the recovery of Ag from the complex [Ag(CN)₂]– Reason: Zinc is powerful reducing agent than copper.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryd and f Block elements

Give the correct order of initials T or F for the following statements. Use T if the statement is true and F if it is false. (I) Sulphide ions reacts with Na₂ [Fe(CN)₅(NO)] to form a purple-coloured compound Na₄ [Fe(C…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryd and f Block elements

Philosopher’s wool when heated with BaO at 1100ºC gives the compound :

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryd and f Block elements

Spiegeleisen is an alloy of :

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryd and f Block elements

Sodium thiosulphate, Na₂S₂O₃. 5H₂O is used in photography to :

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryd and f Block elements

Assertion : The melting point of Mn is more than that of Fe. Reason : Mn has higher number of unpaired e– than Fe in atomic state.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryd and f Block elements

Assertion : Hg is the only metal that is liquid at 0ºC. Reason : It has a very high I.P. and weak metallic bond.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The IUPAC name for [Be₄O(CH₃COO)₆] is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following coordination compounds would exhibit optical isomerism?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

For the square planar complex [M (a) (b) (c) (d)] (where, M = central metal and a, b, c and d are monodentate ligands), the number of possible geometrical isomers are

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Consider the following complex ions, P, Q and R. P = [FeF₆]3- , Q = [V(H₂O)₆]2+ and R = [Fe(H₂O)₆]2+ The correct order of the complex ions, according to their spin-only magnetic moment values (in BM) is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Among [NiCO)₄], [NiCl₄]2–, [Co(NH₃)₄Cl₂] Cl, Na₃ [CoF₆], Na₂O₂ and CsO₂, the total number of paramagnetic compounds is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

In Fe(CO)₅, the Fe – C bond possesses

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Among [NiCO)₄], [NiCl₄]2–, [Co(NH₃)₄Cl₂] Cl, Na₃ [CoF₆], Na₂O₂ and CsO₂, the total number of paramagnetic compounds is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following compounds shows optical isomerism ?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following has an optical isomer ?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which one of the following has largest number of isomers? (R = alkyl group, en = ethylenediamine)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which one of the following complex ions has geometrical isomers ?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Exhibits temperature dependent magnetic behaviour (paramagnetic/diamagnetic) the coordination geometries of Ni²⁺ in the paramagnetic and diamagnetic states are respectively

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Match each set of hybrid orbitals from LIST-I with complex(es) given is LIST-II LIST-I LIST-II (P) dsp2 (1) [FeF₆]4– (Q) sp3 (2) [Ti(H₂O)₃Cl₃] (R) sp3d2 (3) [Cr(NH₃)₆]3+ (S) d2sp3 (4) [FeCl₄]2– (5) Ni(CO)₄ (6) [Ni(CN)…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Match the list I and list II and pick the correct matching from the codes given below: List I List II (Complex) (Structure and magnetic moment) A. [Ag(NH₃)₂]+ 1. Square planar and 1.73 BM B. [Co(NH₃)₆]3+ 2. Linear and…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

What is (are) number(s) of unpaired electrons in the square planar [Pt(CN)₄]2– ion?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following is not considered as an organometallic compound?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Four transition metal octahedral complexes, (the choice given below) low spin electron configurations arises only for

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