HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compoundsAchiever Section

Consider the following complex ions, P, Q and R. P = [FeF₆]3- , Q = [V(H₂O)₆]2+ and R = [Fe(H₂O)₆]2+ The correct order of the complex ions, according to their spin-only magnetic moment values (in BM) is

A.R < Q < P
B.Q < R < P✓ Correct
C.R < P < Q
D.Q < P < R
Explanation

Number of unpaired electrons in P = Fe³⁺ = 5 Number of unpaired electrons in Q = V²⁺ = 3 Number of unpaired electrons in R= Fe²⁺ = 4 All the ligands mentioned here are weak field ligands, Hence, the number of the unpaired electrons will remains same as there will be no pairing of the electrons. μ= n(n+2)BM Hence, the correct answer is option (b).

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