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MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

Assertion: Chloral reacts with phenyl chloride to form DDT. Reason: It is an electrophilic substitution reaction

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

Assertion: A dichlorobenzene is slightly more reactive than chlorobenzene towards an aromatic nucleophilic substitution reaction. Reason: Chlorine has electron withdrawing effect on aromatic ring.

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

Which of the following bases would give the best yield for the substitution product when reacted with 2-chloropropane?

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

Assertion: Consider the following synthesis CH3ONa + PhBr Path–II yields better yield of product than Path-I. Reason: CH3ONa is stronger base than PhONa.

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

Assertion: Benzyl bromide when kept in acetone – water, produces benzyl alcohol. Reason: The reaction follows SN2 mechanism.

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

Which of the following species is an electrophile?

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

Which of the following species is an electrophile?

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

Which of the following species is a nucleophile?

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

Which of the following species is a nucleophile? (a) CH O

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

Which of the following species is a nucleophile?

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

Which of the following species is a nucleophile?

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

The decreasing order of nucleophilicity among the nucleophiles

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

Consider the following groups (I) — OCOCH3 (II) — OCH3 (III) — OSO2CH3 (IV) — OSO2CF3 The decreasing order of their leaving ability is

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

Among these nucleophiles, which of the following orders is correct for their nucleophilicity order in gas phase? - CH , NH , OH ,F (a) - CH >NH >OH >F (b) F OH NH CH (c) - OH >NH >F >CH

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

Θ Θ Θ Θ C H , N H ,O H,F Among these nucleophiles, which of the following orders is correct for their nucleophilicity in acetone? (a) Θ Θ Θ Θ CH N H O H> F (b) F OH NH CH (c) Θ Θ Θ Θ O H> N H F CH

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

The order of reactivities of the following alkyl halides for a SN2 reaction is

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

Major product of the following reaction is: (a) (b) (c) (d)

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

(a) (b) (c) (d)

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

This reaction would follow which of the following pathway predominantly?

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

C6H6Cl6 is six membered cyclic compound in which each carbon carry one chlorine atom, on treatment with alcoholic KOH yields

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

1-pentene will be formed as major product when methoxide reacts with

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

What is true about the following reaction? (a)Only substitution product is formed. (b)Only elimination product is formed. (c)Both substitution and elimination products are formed and substitution dominates. (d)Both su…

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

The major alkene obtained when this alkyl halide is subjected to E1 reaction will be (a) (b) (c)

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

The major product obtained when this substrate is subjected to E1 reaction will (a) (b) (c)

MEDIUMMCQ SINGLENEET ChemistryInorganic ChemistryAlkyl and Aryl Halides

The major product obtained when this substrate is subjected to E1 reaction will be (a) (b) (c)

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