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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

Ice and water kept in a perfectly insulated thermos flask (no exchange of heat between its contents and the surroundings) at 273 K and the atmospheric pressure are in equilibrium state and the system shows

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

Solid Liquid Liquid Gas Solid Gas The above examples are called

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

Equilibrium involving ions in aqueous solutions is called as

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

The stage of the system is the dynamic equilibrium in which

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

Equilibrium can be established for

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

Purification of camphor involves

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

H O l H O vap. In this equation, the double half arrows indicate that

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

Which of the following is correct for equilibrium state?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

Equilibria involving O2 molecules and the protein heamoglobin play a crucial role

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

For the reaction : N (g) O (g) NO(g) If pressure is increased by reducing the volume of the container, then

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

Au(s) Au(l) Above equilibrium is favoured at

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

When a gas “X” is dissolved in water, the heat is evolved. Then solubility of ‘X’ will increase at

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

If for a particular reversible reaction : Kc = 57 at 355ºC and Kc = 69 at 450º, then

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

For exothermic reaction is Sº < 0, then the sketch of log K vs 1/T may be (a) (b) (c) (d)

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

If standard heat of dissociation of PCl5 is 230 cal, then slope of the graph of log k vs 1 T is

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

Assertion : For PCl5(g) PCl3(g) + Cl2(g). If more Cl2 is added, the equilibrium will shift in backward direction hence equilibrium constant will decrease. Reason : Addition of inert gas to the equilibrium mixture at…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

In a 1.0 L aqueous solution when the reaction (aq) (s) 2 Ag Cu (aq) (s) Cu 2 Ag reaches equilibrium, [Cu2+] = x M and [Ag+] = y M. If the volume of solution is doubled by adding water, then at equilibrium : (a) x …

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

Variation of log K with 1 T is shown by the following graph. Hº for the reaction will be :

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

In each of the following, total pressure set-up at equilibrium is assumed to be equal and is one atm with equilibrium constants KP given : I :CaCO3 (s) CaO (s) + CO2 (g), K1 II : NH4HS (s) NH3 (g) + H2S (g), K2 III :…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

For the chemical equilibrium, CaCO (s) CaO(s) CO (g) , Hº can be determined from which one of the following graphs ? (a) (b) (c) (d)

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

If for the heterogeneous equilibrium CaCO3(s) CaO(s) + CO2 (g) ; K = 1 at 1 atm, the temperature is given by : (a) Sº T Hº (b) Hº T Sº (c) Gº T R (d) Gº T Hº

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

In reversible reaction k k A B , the initial concentration of A and B are a and b in moles per litre and the equilibrium concentration are (a – x) and (b + x) respectively ; express x in terms of k1, k2, a and b. (a…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

For the all gas reaction at 1000 K : 2HI H2 + I2, K = 0.0344. If you were to begin with 8.0 M of HI in a fixed volume container, what would be the equilibrium concentration of H2 ?

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

Consider the reaction NaBr(aq) + H2SO4(aq) NaHSO4(aq) + HBr(aq). The equilibrium constant is 8.3 × 10 –2. If the equilibrium concentrations of NaBr, H2SO4 and NaHSO4 are 6.0 M, 9.0 M and 3.0 M respectively, what is th…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical Equilibrium

When A2 and B2 are allowed to react, the equilibrium constant of the reaction at 27ºC is found (Kc = 4). A2(g) + B2(g) 2AB(g) What will be the equilibrium concentration of AB ?

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