19,000+ solved questions for JEE Advanced, JEE Mains, NEET & IChO — with answers and expert explanations.
Ice and water kept in a perfectly insulated thermos flask (no exchange of heat between its contents and the surroundings) at 273 K and the atmospheric pressure are in equilibrium state and the system shows
Solid Liquid Liquid Gas Solid Gas The above examples are called
Equilibrium involving ions in aqueous solutions is called as
The stage of the system is the dynamic equilibrium in which
Equilibrium can be established for
Purification of camphor involves
H O l H O vap. In this equation, the double half arrows indicate that
Which of the following is correct for equilibrium state?
Equilibria involving O2 molecules and the protein heamoglobin play a crucial role
For the reaction : N (g) O (g) NO(g) If pressure is increased by reducing the volume of the container, then
Au(s) Au(l) Above equilibrium is favoured at
When a gas “X” is dissolved in water, the heat is evolved. Then solubility of ‘X’ will increase at
If for a particular reversible reaction : Kc = 57 at 355ºC and Kc = 69 at 450º, then
For exothermic reaction is Sº < 0, then the sketch of log K vs 1/T may be (a) (b) (c) (d)
If standard heat of dissociation of PCl5 is 230 cal, then slope of the graph of log k vs 1 T is
Assertion : For PCl5(g) PCl3(g) + Cl2(g). If more Cl2 is added, the equilibrium will shift in backward direction hence equilibrium constant will decrease. Reason : Addition of inert gas to the equilibrium mixture at…
In a 1.0 L aqueous solution when the reaction (aq) (s) 2 Ag Cu (aq) (s) Cu 2 Ag reaches equilibrium, [Cu2+] = x M and [Ag+] = y M. If the volume of solution is doubled by adding water, then at equilibrium : (a) x …
Variation of log K with 1 T is shown by the following graph. Hº for the reaction will be :
In each of the following, total pressure set-up at equilibrium is assumed to be equal and is one atm with equilibrium constants KP given : I :CaCO3 (s) CaO (s) + CO2 (g), K1 II : NH4HS (s) NH3 (g) + H2S (g), K2 III :…
For the chemical equilibrium, CaCO (s) CaO(s) CO (g) , Hº can be determined from which one of the following graphs ? (a) (b) (c) (d)
If for the heterogeneous equilibrium CaCO3(s) CaO(s) + CO2 (g) ; K = 1 at 1 atm, the temperature is given by : (a) Sº T Hº (b) Hº T Sº (c) Gº T R (d) Gº T Hº
In reversible reaction k k A B , the initial concentration of A and B are a and b in moles per litre and the equilibrium concentration are (a – x) and (b + x) respectively ; express x in terms of k1, k2, a and b. (a…
For the all gas reaction at 1000 K : 2HI H2 + I2, K = 0.0344. If you were to begin with 8.0 M of HI in a fixed volume container, what would be the equilibrium concentration of H2 ?
Consider the reaction NaBr(aq) + H2SO4(aq) NaHSO4(aq) + HBr(aq). The equilibrium constant is 8.3 × 10 –2. If the equilibrium concentrations of NaBr, H2SO4 and NaHSO4 are 6.0 M, 9.0 M and 3.0 M respectively, what is th…
When A2 and B2 are allowed to react, the equilibrium constant of the reaction at 27ºC is found (Kc = 4). A2(g) + B2(g) 2AB(g) What will be the equilibrium concentration of AB ?