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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Decomposition of ammonium nitrite is an example of

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The number of reacting species (atoms, ions or molecules) taking part in an elementary reaction, which must collide simultaneously in order to bring about a chemical reaction is called …A… of a reaction Here, A refer to

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The following mechanism has been proposed for a reaction. 2P Q R S P Q T R Slow P T R fast -> -> -> The rate law expression for the reaction is (a) r k P Q (b) r k P (c) r k P T (d) r k P Q

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a reaction, 2NO 2H N 2H O, -> the possible mechanism is 2NO N O slow N O H N O H O -> fast N O H N H O -> What is the rate law and order of the reaction? (a) Rate = [N2O2], order =

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The chemical reaction, proceeds as O O [O] (fast) [O] O 2O -> (slow) The rate law expression will be

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In the sequence of reaction k k k A B C D -> -> -> k3 > k2 > k1, then the rate determining step of the reaction is :

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The overall rate of the reaction is controlled by the ______ step in a reaction. Choose the suitable word to fill the blank.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the reaction 2A + B ⟶ D + E the following mechanism has been proposed : A + B ⟶ C + D (slow) A + C ⟶ E (fast) The rate law expression for the reaction is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

…A… reactions involves a sequence of elementary reactions in the formation of product. Here, A refers to

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The reactions taking place in one step are called …A… reactions. Here, A is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In a first-order reaction A B -> , if k is rate constant and initial concentration of the reactant A is 0.5 M, then the half-life is. (AIPMT 2007)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

If 60% of a first order reaction was completed in 60 minutes, 50% of the same reaction would be completed in approximately. (AIPMT 2007)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

According to collision theory of reaction rates, the rate of reaction depends

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rates of reactions increase with increase of temperature because

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

What will happen, on increasing the temperature or decreasing the activation energy (answer on the basis of Arrhenius equation)?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In the Arrhenius equation, a E /RT k Ae , the factor a E /RT e corresponds to the

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

On the basis of Arrhenius equation mentioned in Above ques. consider the following statements. I.Ea is activation energy. II.Unit of Ea is J mol-1 III.R is gas constant. Which of these are true statements?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In Arrhenius equation mentioned in Above Ques. ‘A’ is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The correct form of Arrhenius equation is (a) a E /RT k Ae (b) a RT/E k Ae (c) a E /RT k Ae (d) a RT/E k Ae

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The first order rate constant for a certain reaction increases from 1.667 × 10–6 s–1 at 727ºC to1.667 × 10–4 s–1 at 1571ºC. The rate constant at 1150ºC, assuming constancy of activation energy over the given temperatu…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate constant of a reaction is given by ln k (sec–1) = 14.34 – (1.25 × 104)/T What will be the energy of activation?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate of reaction is doubled for every 10ºC rise in temperature. The increase in rate as result of increase in temperature from 10ºC to 100ºC is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a chemical reaction with rise in temperature by 10oC, the rate constant is nearly …A…, Here, A refers to

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Most of the chemical reactions are accelerated by …A… in temperature. Here, A refers to

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The initial concentration of N2O5 in the following order reaction, N O g 2NO g g -> was 1.24 10 molL x at 318 K. The concentration of N2O5 after 60 min was 0.20 × 10-2 mol L-1. Calculate the rate constant of the…

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