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MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

…A… of the reaction is the time in which the concentration of a reactant is reduced to one half of its initial concentration. Choose the appropriate word to fill ‘A’ from the options given below.

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

Assertion (A) Molecularity of a reaction can have a fractional value. Reason (R) Order of a reaction can have a fractional value.

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

Assertion (A) The reaction, H Br 2HBr -> has a molecularity of two. Reason (R) Order of reaction is 3/2.

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

The reaction, 2N O 4NO O is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

Four reactions are given below. Which one of them is of zero order? (a) PCl PCl Cl -> (b) 2FeCl SnCl 2FeCl SnCl -> (c) H Cl 2HCl -> (d) N O 2NO O -> Ans. (c) Sol. The order of all photochemical reactions is zero …

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

Choose the correct answer out of the following choices. Assertion (A) Order and molecularity are different. Reason (R) Order can be determined experimentally and molecularity is the sum of the stoichiometric coefficie…

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

Choose the correct answer out of the following choices. Assertion (A) Some zero order reactions may have order in fractions. Reason (R) Order cannot be determined from balanced chemical equation.

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

Which of the following statement(s) is/are correct about order of a reaction? I.The order of a reaction can be a fractional number. II.Order of a reaction is experimentally determined quantity. III.The order of a reac…

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

Consider the data given below for a hypothetical reactions M N -> Times(s) Rate of reaction (mol L-1 s-1) 4.20 × 10-4 4.20 × 10-4 4.20 × 10-4 4.20 × 10-4 4.18 × 10-4 For the above data, the order of reaction is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

Statement I For a complex reaction, order is given by the slowest step of the reaction. Statement II Molecularity of the slowest step is same as the order of the overall reaction. Which of these statement(s) is/are tr…

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

2NO O 2NO ->

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

2HI H I -> C. Trimolecula r

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

NH NO N 2H O -> B. Bimolecular

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

NH NO N 2H O -> A B C (a) (b) (c) (d)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

2NO O 2NO -> C. Trimolecular

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

2HI H I -> B. Bimolecular

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

What is true about pseudo first order reaction?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

Match the following Columns and choose the correct option from the codes given below. Column I (Type of reaction) Column II (Example) A. Unimolecular

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

For a reaction, A B -> product, the rate law is given by, 1/2 r k A B . what is the order of the reaction?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

For the rate expression rate 3/2 k A B the overall order of a reaction is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

In the presence of acid, the initial concentration of cane-sugar was reduced from 0.2 M to 0.1 M in 5 hrs and to 0.05 M in 10 hrs. The reaction must be of

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

Which of the following statements is false?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

For a simple reaction, 2P Q R S, -> molecularity will be

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

In the graph shown below ‘I’ means

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kinetics

Energy of activation of an exothermic reaction is

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