Chemistry Question Bank

The unit of rate constant for a zero-order reaction is. (AIPMT 2011 M)

Assertion (A) Molecularity of a reaction can have a fractional value. Reason (R) Order of a reaction can have a fractional value.

Assertion (A): The order of a reaction can have fractional value. Reason (R): The order of a reaction cannot be written from balanced equation of a reaction.

Assertion (A): In rate law, unlike in the expression for equilibrium constants, the exponents for concentrations do not necessarily match the stoichiometric coefficients. Reason (R): It is the mechanism and not the ba…

Choose the correct answer out of the following choices. Assertion (A): Most people think diamond is forever. Reason (R): Conversion rate of diamond to graphite is very low.

Collision theory is used to explain how chemical species undergo a reaction. Using this theory and the kinetic molecular model, which of the following does NOT influence the rate of a chemical reaction?

For a first order reaction A P, the temperature (T) dependent rate constant (k) was found to follow the equation 1 logk 6.0 T . The pre- exponential factor A and the activation energy Ea, respectively are: (a) 1.0…

An endothermic reaction with high activation energy for the forward reaction is given by the diagram : (a) (b) (c) E E (d)

The potential energy diagram for a reaction R P -> is given below o H of the reaction corresponds to the energy:

Ea and H values of reactions R1, R2, R3 and R4 carried out at the same temperature are as given below: R1 Ea = 40 kJ mol–1, H = – 80 kJ mol–1 R2 Ea = 20 kJ mol–1, H = – 30 kJ mol–1 R3 Ea = 60 kJ mol–1, H = + 40 kJ mol…

The hypothetical reaction A B 2AB; -> follows the following mechanism Fast A A A, -> Slow Fast A B AB B,A B AB. -> -> The order of the overall reaction is

The initial rates of reaction 3A + 2B + C -> Products, at different initial concentrations are given below: Initial rate M s–1 [A]0 , M [B]0 , M [C]0 , M 5.0 × 10–3 0.010 0.005 0.010 5.0 × 10–3 0.010 0.005 0.015 1.0 ×…

For the reaction : sunlight H Cl 2HCl ->

From the following data find rate constant of decomposition of H2O2 in aqueous solution Time (in minutes) Volume (in cc of KMnO4) 22.8 13.3 8.25

1 mL of ethyl acetate was added to a flask containing 20 mL of N/20 HCl maintained at 25oC. 2 mL of the reaction mixture were withdrawn at different intervals and titrated with a standard alkali solution. The followin…

The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume. 2(g) 2(g) 2(g) SO Cl SO Cl -> Experimen t Time/s-1 Total pressure/atm 0.5 0.6 What is the rate of reaction…

Select the rate law that corresponds to the data shown for the following reaction A B C -> Expt. (A) (B) Initial rate 0.012 0.035 0.10 0.024 0.070 0.80 0.024 0.035 0.10 0.012 0.070 0.80

With passage of time, the concentration of reactants …A… and rate of reaction …B… . Here A and B are

For the reaction 4 A B C D -> , which of the following statement is not correct ?

For a reaction A → B, enthalpy of reaction is -4.2 kJ mol-1 and enthalpy of activation is 9.6 kJ mol-1. The correct potential energy profile for the reaction is shown in option. (NEET 2021) (a) (b) (c) (d)

The slope of Arrhenius plot (ln k v/s 1/T) of first order reaction is 5 10 . K x The value of a E of the reaction is. Choose the correct option for your answer. (Given R = 8.314 Jk-1 mol-1) (NEET 2021)

An increase in the concentration of the reactants of a reaction leads to change in: (NEET 2020)

The rate constant for a first order reaction is 4.606 10 s x . The time required to reduce 2.0 g of the reactant to 0.2 g is: (NEET 2020)

The half-life for a zero order reaction having 0.02 M intial concetration of reactant is 100 s. The rate constant (in mol L-1 s-1) for the reaction (NEET 2020) (a) 1.0 10 x (b) 2.0 10 x (c) 2.0 10 x (d) 1.0 10 x

If the rate constant for a first order reaction is k, the time (t) required for the completion of 99% of the reaction is given by: (NEET 2019)