19,000+ solved questions for JEE Advanced, JEE Mains, NEET & IChO — with answers and expert explanations.
Half-lives of a first order and a zero order reaction are same. Then the ratio of the initial rates of first order reaction to that of the zero order reaction is (a) 0.693
T50 of first -order reaction is 10 min. Starting with 10 mol L–1, rate after 20 min is
A reaction which is of first order w.r.t. reactant A, has a rate constant 6 min–1. If we start with [A] = 0.5 mol L–1, when would [A] reach the value of 0.05 mol L–1
The following data pertains to reaction between A and B : S. No. [A] mol L–1 [B] mol L–1 Rate (mol L–1 time–1) 1 1.0 × 10–2 2.0 × 10–2 2.0 × 10–4 2 2.0 × 10–2 2.0 × 10–2 4.0 × 10–4 3 2.0 × 10–2 4.0 …
For the following reaction: NO2(g) + CO(g) ->NO(g) + CO2(g), the rate law is: Rate = k [NO2]2.If 0.1 mole of gaseous carbon monoxide is added at constant temperature to the reaction mixture which of the following stat…
For a reaction, activation energy Ea = 0 and the rate constant at 200 K is 1.6 × 106 s–1. The rate constant at 400 K will be: [Given that gas constant R=8.314 J K–1 mol–1] (Odisha NEET 2019)
Formula for half-life of a zero order reaction is (JIPMER 2019) (a) C k (b) C 2k (c) 2C k (d) 2C 2k
If half-life of a substance is 36 minutes. Find amount left after 2 hrs. Initial amount is 10 g. (JIPMER 2019)
Find out time period of Ist order reaction when reaction complete 2/3rd, if the value of rate constant is 4.3 10 s x (JIPMER 2019) (a) 0.0025 10 sec x (b) 0.25 10 sec x (c) 0.025 10 sec x (d) 2.5 10 sec x
The correct difference between first and second order reactions is that (NEET 2018)
The addition of a catalyst during a chemical reaction alters which of the following quantities? (NEET 2016)
The decomposition of phosphine (PH3) on tungsten at low pressure is a first-order reaction. It is because the: (NEET II 2016)
The rate constant of the reaction A ->B is 0.6 × 10–3 mol L-1 second-1. If the concentration of A is 5 M then concentration of B after 20 minutes is: (NEET 2015 RS)
When initial concentration of a reactant is doubled in a reaction, its half-life period is not affected. The order of the reaction is: (NEET 2015)
The activation energy of a reaction can be determined from the slope of which of the following graphs? (NEET 2015)
The inversion of cane sugar is first order in [sugar] and proceeds with half-life of 600 minutes at pH = 4 for a given concentration of sugar. However, if pH = 5, the half-life changes to 60 minutes. The rate law expr…
A reaction is 50% completed in 2 hours and 75% completed in 4 hours. The order of reaction is (NEET Kar. 2013)
With passage of time, the concentration of reactants …A… and rate of reaction …B… . Here A and B are
Choose the correct answer out of the following choices. Assertion (A): Most people think diamond is forever. Reason (R): Conversion rate of diamond to graphite is very low.
Collision theory is used to explain how chemical species undergo a reaction. Using this theory and the kinetic molecular model, which of the following does NOT influence the rate of a chemical reaction?
For a first order reaction A P, the temperature (T) dependent rate constant (k) was found to follow the equation 1 logk 6.0 T . The pre- exponential factor A and the activation energy Ea, respectively are: (a) 1.0…
An endothermic reaction with high activation energy for the forward reaction is given by the diagram : (a) (b) (c) E E (d)
The potential energy diagram for a reaction R P -> is given below o H of the reaction corresponds to the energy:
Select the rate law that corresponds to the data shown for the following reaction A B C -> Expt. (A) (B) Initial rate 0.012 0.035 0.10 0.024 0.070 0.80 0.024 0.035 0.10 0.012 0.070 0.80
For the reaction 4 A B C D -> , which of the following statement is not correct ?