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HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Half-lives of a first order and a zero order reaction are same. Then the ratio of the initial rates of first order reaction to that of the zero order reaction is (a) 0.693

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

T50 of first -order reaction is 10 min. Starting with 10 mol L–1, rate after 20 min is

HARDINTEGERIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

A reaction which is of first order w.r.t. reactant A, has a rate constant 6 min–1. If we start with [A] = 0.5 mol L–1, when would [A] reach the value of 0.05 mol L–1

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

The following data pertains to reaction between A and B : S. No. [A] mol L–1 [B] mol L–1 Rate (mol L–1 time–1) 1 1.0 × 10–2 2.0 × 10–2 2.0 × 10–4 2 2.0 × 10–2 2.0 × 10–2 4.0 × 10–4 3 2.0 × 10–2 4.0 …

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

For the following reaction: NO2(g) + CO(g) ->NO(g) + CO2(g), the rate law is: Rate = k [NO2]2.If 0.1 mole of gaseous carbon monoxide is added at constant temperature to the reaction mixture which of the following stat…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

For a reaction, activation energy Ea = 0 and the rate constant at 200 K is 1.6 × 106 s–1. The rate constant at 400 K will be: [Given that gas constant R=8.314 J K–1 mol–1] (Odisha NEET 2019)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Formula for half-life of a zero order reaction is (JIPMER 2019) (a) C k (b) C 2k (c) 2C k (d) 2C 2k

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

If half-life of a substance is 36 minutes. Find amount left after 2 hrs. Initial amount is 10 g. (JIPMER 2019)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Find out time period of Ist order reaction when reaction complete 2/3rd, if the value of rate constant is 4.3 10 s x (JIPMER 2019) (a) 0.0025 10 sec x (b) 0.25 10 sec x (c) 0.025 10 sec x (d) 2.5 10 sec x

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

The correct difference between first and second order reactions is that (NEET 2018)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

The addition of a catalyst during a chemical reaction alters which of the following quantities? (NEET 2016)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

The decomposition of phosphine (PH3) on tungsten at low pressure is a first-order reaction. It is because the: (NEET II 2016)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

The rate constant of the reaction A ->B is 0.6 × 10–3 mol L-1 second-1. If the concentration of A is 5 M then concentration of B after 20 minutes is: (NEET 2015 RS)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

When initial concentration of a reactant is doubled in a reaction, its half-life period is not affected. The order of the reaction is: (NEET 2015)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

The activation energy of a reaction can be determined from the slope of which of the following graphs? (NEET 2015)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

The inversion of cane sugar is first order in [sugar] and proceeds with half-life of 600 minutes at pH = 4 for a given concentration of sugar. However, if pH = 5, the half-life changes to 60 minutes. The rate law expr…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

A reaction is 50% completed in 2 hours and 75% completed in 4 hours. The order of reaction is (NEET Kar. 2013)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

With passage of time, the concentration of reactants …A… and rate of reaction …B… . Here A and B are

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Choose the correct answer out of the following choices. Assertion (A): Most people think diamond is forever. Reason (R): Conversion rate of diamond to graphite is very low.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Collision theory is used to explain how chemical species undergo a reaction. Using this theory and the kinetic molecular model, which of the following does NOT influence the rate of a chemical reaction?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

For a first order reaction A P, the temperature (T) dependent rate constant (k) was found to follow the equation 1 logk 6.0 T . The pre- exponential factor A and the activation energy Ea, respectively are: (a) 1.0…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

An endothermic reaction with high activation energy for the forward reaction is given by the diagram : (a) (b) (c) E E (d)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

The potential energy diagram for a reaction R P -> is given below o H of the reaction corresponds to the energy:

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Select the rate law that corresponds to the data shown for the following reaction A B C -> Expt. (A) (B) Initial rate 0.012 0.035 0.10 0.024 0.070 0.80 0.024 0.035 0.10 0.012 0.070 0.80

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

For the reaction 4 A B C D -> , which of the following statement is not correct ?

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