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MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Among TiF6 2-, CoF6 3-, Cu2Cl2 and NiCl4 2- (atomic numbers of Ti = 22, Co = 27, Cu = 29, Ni = 28), the colourless species are

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

[Sc(H2O)6]3+ ion is

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Among [Ni(CO)4], [Ni(CN)4]2– and [NiCl4]2–

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The compound which does not show paramagnetism is

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Which of the following complex ions/molecules of nickel is paramagnetic?

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Which of the following is diamagnetic?

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Which of the following octahedral complex ions is diamagnetic?

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Which of the following complex ions is diamagnetic?

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Which of the following complex ions is paramagnetic?

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The structures of Ni(CO)4 and Ni(PPh3)2Cl2 are

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Which of the following statements is correct?

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The formation of the complex ion [Co(NH3)6]3+ involves sp3d2 hybridization of Co3+. Hence, the complex ion should possess

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The hybridization states of the central atom in the complex ions [FeF6]3–, [Fe(H2O)6]3+ and [Ni(NH3)6]2+ are

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The hybridization states of the central atom in the complexes Fe(CN)6 3–, Fe(CN)6 4– and CO(NO2)6 3– are

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Which one of the following has a square planar geometry? (At. no. Co = 27, Ni = 28, Fe = 26, Pt = 78)

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The magnetic moment of a complex ion is 2.83 BM. The complex ion is

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The value of magnetic moment for a complex ion is 1.73 BM. The complex. ion is

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Among the following ions, which one has the highest paramagnetism?

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

An octahedral complex is formed when hybrid orbitals or the following type are involved

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Which of the following complex ions obeys Sidgwick‘s effective atomic number (EAN) rule?

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The effective atomic number for the complex ion [Pd(NH3)6]4+ is

HARDMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

The total number of possible isomers of the complex compound [CuII(NH3)4][PtIICl4] is

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Which of the following ion does not follow EAN rule?

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Mn H O 25–2 12 . Thus it violates EAN rule. Pt NH Fe CN 78 – 4 12 24+0 12 Fe CO 26+ 0 10

MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryCoordination compounds

Which of the following complex ions violates the EAN rule?

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