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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The correct order of magnetic moments (spin only values in B.M.) is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Among the following complexes, which has a magnetic moment 5.9 BM ? Ni(CO)4, [Fe(H2O)6]2+, [Co(NH3)6]3+, [MnBr4]2–, [Zn(NH3)4]2+

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Choose the correct statement

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Among TiF6 2-, CoF6 3-, Cu2Cl2 and NiCl4 2- (atomic numbers of Ti = 22, Co = 27, Cu = 29, Ni = 28), the colourless species are

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The compound having tetrahedral geometry is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The crystal field splitting energy for octahedral ( ) and tetrahedral ( t ) complexes is related as (a) t (b) t (c) t (d) t

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The magnitude of crystal field stabilization energy in tetrahedral complexes (CFSE of t ) is considerably less than that in the octahedral field because

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Cr3+ form four complexes with four different ligands which are [Cr(Cl)6]3–, [Cr(H2O)6]3+, [Cr(NH3)6]3+ and [Cr(CN)6]3–. The order of CFSE (0) in these complexes is in the order :

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The geometry of Ni(CO)4 and Ni(PPh3)2Cl2 are [Manipal 2006]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

[Cr(H2O)6]Cl3 (at. no. of Cr = 24) has a magnetic moment of 3.83 BM, the correct distribution of 3d- electrons in the chromium of the complex is [CBSE AIPMT 2006] (a) xz x -y , x 3d 3d ,3d (b) xy x -y , 3d ,3d 3d , yz…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The pair in which both species have same magnetic moment (spin only value) is [AIIMS 2006]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The number of possible isomers of an octahedral complex [Co(C2O4)2 (NH3)2]– is [AIIMS2006]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Among the following, the species having square planar geometry for central atom are [AIIMS2006] (i) XeF4 (ii) SF4 (iii) [NiCl4] 2– (iv) [PtCl4] 2–

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

In which of the following coordination entities the magnitude of o (CFSE in octahedral field) will be maximum? (At. no. Co = 27) [CBSE AIPMT2007]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following will give a pair of enantiomorphs? (en = NH2CH2CH2NH2) [CBSE AIPMT 2007]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Among the following, the compound that is both paramagnetic and coloured is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The d-electron configuration of Cr 2+, Mn 2+, Fe 2+ and Co 2+ are d 4, d 5, d 6 and d 7 respectively. Which one of the following will exhibit minimum paramagnetic behaviour? [CBSE AIPMT 2007]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The pair having the same magnetic moment is: [At, No. : Cr = 24, Mn = 25, Fe = 26, Co = 27]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Among [NiCO4], [Ni(CN)4]2–, [NiCl4]2– species, the hybridisation states of the Ni atom are, respectively (At. no. of Ni = 28)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The geometry of Ni (CO)4 and and Ni (P Ph3)2 Cl2 are

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The correct order of magnetic moments (spin only) values in BM) among the following is (Atomic number: Mn = 25, Fe = 26, Co = 27)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which one of the following is wrongly matched?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following complex ions, which is diamagnetic in nature? [CBSE AIPMT 2008]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following is a double salt?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

When potash alum is dissolved in water, the total number of ions produced is

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