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19,000+ solved questions for JEE Advanced, JEE Mains, NEET & IChO — with answers and expert explanations.

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HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

The reduction potential at 25oC for Fe3+|Fe2+ electrode is +0.718 V. If , the ratio of molar concentrations of Fe2+ to Fe3+ ions in solution is (2.303RT/F = 0.06, log 5 = 0.7)

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

For the process: Cu2+ + 2e– → Cu; log[Cu2+] vs. Ered graph is shown in the figure, where OA = 0.34 V. The electrode potential of the half-cell of Cu|Cu2+ (0.1 M) will be [2.303 RT/F = 0.06]

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

Which graph correctly correlates Ecell as a function of concentrations for the cell Zn(s) + 2Ag+(aq) Zn2+(aq) + 2Ag(s), E°cell = 1.56 V Y-axis : Ecell, X-axis : log10 (a) (b) (c) (d)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

Cr O 14H 6e 2Cr 7H O; -> E 1.33V. At [Cr O ]l 4.5 millimoles, [Cr3+] = 15 millimoles, E is 1.067 V. The pH of the solution is nearly equal to [KCET 2016]

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

Standard electrode potential for Sn4+/Sn2+ couple is +0.15 V and that for the Cr3+/Cr couple is –0.74V. These two couples in their standard state are connected to make a cell. The cell potential will be: [AIPMT 2011]

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

For the reduction of silver ions with copper metal, the standard cell potential was found to be +0.46 V at 25ºC. The value of standard Gibbs energy, ∆Gº will be (F = 96500 C mol–1) [CBSE AIPMT 2010]

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

How many coulombs are required to deposit 50 g of aluminium when the electrode reaction is Al 3e Al -> [RPMT 2010]

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

The equivalent conductance of M / 32 solution of a weak monobasic acid is 8.0 mho cm2 eq–1and at infinite dilution is 400 mho cm2 eq–1. The dissociation constant of this acid is [CBSE AIPMT 2010]

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

The conductivity of 0.20 M KCl solution at 298 K is 0.0248 S cm–1. What will be molar conductivity? [Haryana PMT 2010] (a)124 S cm2 (b)124 S cm–1 (c)124 S ohm–1 cm2 equiv–1 (d)124 S cm2 mol–1

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

Which one of the following is not a function of a salt bridge?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

Standard solution of KNO3 is used to make salt bridge because

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

Which of the following has been universally accepted as a reference electrode at all temperatures and has been assigned a value of zero volts?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

The electrochemical cell stops working after some time because

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

Which one of the following statements is incorrect regarding an electrochemical cell?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

Galvanic cell is a device in which

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryElectrochemistry

What is the cell reaction occurring in Daniell cell (Galvanic cell)? (a) Cu s ZnSO aq CuSO aq Zn s -> (b) Zn s CuSO aq Cu s ZnSO -> (c) Ni s ZnSO aq NiSO s Zn s -> (d) 2Na s CdSO aq Na SO aq…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryElectrochemistry

Assertion: Zinc can be used while copper cannot be used in the recovery of Ag from the complex [Ag(CN)2]– Reason: Zinc is powerful reducing agent than copper.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryElectrochemistry

When iron is rusted, it is [MP PMT 2010]

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryElectrochemistry

At 18º C, the conductance of H+ and CH3COO– at infinite dilution are 315 and 35 mho cn2 eq–1 respectively. The equivalent conductivity of CH3 COOH at infinite dilution is…..mho cm2 eq–1 [CBSE AIPMT 2010]

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryElectrochemistry

Assertion (A) On dilution, the equivalent as well as molar conductivity of solution increases. Reason (R) With dilution, the number of current carrying particles per cm3 increases. [AIIMS 2010]

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryElectrochemistry

Which of the following expressions correctly represents the equivalent conductance at infinite dilution of Al2(SO4)3, Given that o Al and o SO are the equivalent conductance at infinite dilution of the respective …

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryElectrochemistry

Standard electrode potential of cell is (EºAg+/Ag = 0.80V)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryElectrochemistry

If the salt bridge is removed suddenly from a working cell, the voltage

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryElectrochemistry

Which one of the following is not a function of a salt bridge?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryElectrochemistry

Which one of the following statements is incorrect regarding an electrochemical cell?

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