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HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Reduction of 2-butyne with sodium in liquid ammonia gives predominantly :

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

The product A, is (a) (b) (c) (d)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Acetylenic hydrogens are acidic because

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

CH CH CH

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

CH CH C CH

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Consider the below reaction and identify the missing reagent/chemical (NEET 2021) + NaOH + ? CH CH COO Na Heat CH CH Na CO ->

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

The major product formed in dehydrohalogenation reaction of 2-Bromopentane is pent-2-ene. This product formation is based on (NEET 2021)

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

Identify the major product (a) (b) (c) (d)

HARDMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

Assertion: Alkyl benzene is not prepared in good yield by Friedel-Craft’s alkylation of benzene. Reason: Alkyl halides are less reactive than acyl halides.

HARDMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

Assertion: Rates of nitration of benzene and hexadeuterobenzene are different. Reason: The C—H bond is stronger than the C—D bond.

HARDMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

Assertion: Friedel-Craft’s reaction is used to introduce an alkyl or acyl group in the benzene nucleus. Reason: Benzene is a solvent for Friedel-Craft’s alkylation of bromobenzene.

HARDMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

Assertion: Alkynes are more reactive towards nucleophilic addition reaction as compared to alkenes. Reason: Alkynes contain two pi bonds, while alkenes have only one bond.

HARDMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

Assertion:1-butene on reaction with HBr in the presence of a peroxide produces 1-bromobutane. Reason: It involves the formation of a primary radical.

HARDMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

Assertion: The addition of HBr on 2-butene gives two isomeric products. Reason: Addition of HBr on 2-butene follows Markownikoff’s rule.

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

With respect to the conformers of ethane, which of the following statements is true? (NEET 2017)

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

The compound that will react most readily with gaseous bromine has the formula (NEET 2017) (a) C H (b) C H (c) C H (d) C H

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

In which of the following molecules, all atoms are coplanar? (NEET-II 2016) (a) (b) (c) (d)

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

Which of the following can be used as the halide component for Friedel–Crafts reaction? (NEET-II 2016)

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

In the reaction i NaNH /liq.NH ii CH CH Br H C CH X -> i NaNH /liq.NH ii CH CH Br Y -> X and Y are (NEET-I 2016)

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

The pair of electrons in the given carbanion, CH3C≡C–, is present in which of the following orbitals? (NEET-I 2016)

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

Which of the following compounds shall not produce propene by reaction with HBr followed by elimination or direct only elimination reaction? (NEET-II 2016) (a)

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

The correct statement regarding the comparison of staggered and eclipsed conformations of ethane, is (NEET-I 2016)

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

Consider the nitration of benzene using mixed conc. H SO and HNO . If a large amount of KHSO4is added to the mixture, the rate of nitration will be (NEET 2016)

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

Which of the following is not the product of dehydration of (NEET 2015) (a) (b) (c) (d)

MEDIUMMCQ SINGLENEET ChemistryOrganic ChemistryHydrocarbons

In the reaction with HCl, an alkene reacts in accordance with the Markovnikov’s rule to give a product 1-chloro- 1-methyl-cyclohexane. The possible alkene is (NEET 2015) (a) (b)

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