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HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: When aqueous, solution of CH3COOAg is diluted, then its degree of hydrolysis increases. Reason:  Silver  acetate  is  the  salt  of  weak  acid  and weak base; its degree of hydrolysis does not depend on th…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: When aqueous, solution of CH3COONH4 is diluted, then its degree of hydrolysis increases. Reason:  Ammonium  acetate  is  the  salt  of  weak  acid and  weak  base;  its  degree  of  hydrolysis  does  not de…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: Aqueous  solution of  ammonium  carbonate is basic. Reason: Acidic or Basic nature of a salt solution of a salt  of  weak  acid  and  weak  base  depends  on  Ka  and Kb of the acid and base forming it.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: If a K  of HA is 10–3 and a K  of HB is 10 at 25ºC, pH of an aqueous solution of HB will be one unit greater than pH of equimolar solution of HA. Reason:  For  weak  acids,  both  concentration  and ionizat…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: pH of 10–8 M HCl lies between 6 and 7. Reason:  For  very  dilute  solutions  of  acids,  H+  ion contribution from water is also taken into consideration.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: pH  of  water  increases  with  an  increase  in temperature. Reason: Kw  of  water  increases  with  increase  in temperature.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: Addition  of  HCl(aq.)  to  HCOOH(aq.) decreases the ionization of HCOOH. Reason:  Common  ion  effect  of  H+  ion,  reduces  the ionization of HCOOH.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion (A): H2SO4 acts as a base in the presence of HClO4. Reason (R): Perchloric  acid  is  stronger  acid  than H2SO4.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The solubility products of MA, MB, MC and MD are 1.8 × 10–10, 4 × 10–3, 4 × 10–8 and 6 × 10–5 respectively. If  a  0.01  M  solution  of  MX  is  added  dropwise  to  a mixture containing A–, B–, C– and D– ions then t…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Ksp of Mg (OH)2 is 1 × 10–12. 0.01 M Mg (OH)2 will be precipitating at the limiting pH :

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Calculate  the  concentration  of  H+  ion  in  mol/L  of 0.010M solution of NH4Cl? (Kb = 1.8 × 10–6)

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

When one drop of a concentrated HCl is added to 1 L of pure water at 25ºC, the pH drops suddenly from 7 to 4. When the second drop of the same acid is added, the pH of the solution further drops to about

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

A student dissolved 0.100 mol of an unknown monoprotic acid, HA, in sufficient water to make 1.00 L of solution. She measured the pH of the solution as pH = 2.60. Of the following, the acid HA is

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

For  a  “c  molar”  concentrated  solution  of  a  weak electrolyte AxBy, the degree of dissociation is given as (a) (b) (c) (d)

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

What is the equilibrium [OH–] in 0.1413 M H2CO3 ? H CO H O H O HCO (Ka = 4.30 ×10–7)

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

A mixture of weak acid is 0.1 M in HCOOH a K 1.8 10 x and 0.1 M in HOCN a K 3.1 10 x Hence, [H O ]  is

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The equilibrium constant for this reaction is approximately 10–3. HPO (aq.) HCO (aq.) H PO (aq.) CO (aq.) Which is the strongest conjugate base in this reaction? (a) HPO (aq.) (b) HCO (aq.) (c) H PO (aq.) (d…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Concentration of the  Ag ions in a saturated solution of Ag C O  is 2.2 10 mol L . x Solubility product of Ag C O  is (NEET 2017) (a) 2.66 10 x (b) 4.5 10 x (c) 5.3 10 x (d) 2.42 10 x

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

MY  and  NY3.  Two  nearly  insoluble  salts,  have  the same sp K value  of  6.2  x  10-15  at  room  temperature. Which  statement  would  be  true  in  regard  to  MY  and NY3? (NEET-I 2016)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The solubility of AgCl with solubility product 1.6x10-10 in 0.1 M NaCl solution would be (NEET- II 2016)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Which  of  the  following  fluoro-compounds  is  most likely to behave as a Lewis’s base?  (NEET-II 2016)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The  percentage  of  pyridine (C H N)   that  forms pyridinium  ion (C H N H) in  a  0.10  M  aqueous pyridine solution ( b K  for C H N 1.7 10 ) x is (NEET 2016)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

What  is  the  pH  of  the  resulting  solution  when  equal volumes of 0.1 M NaOH  and 0.01  M HCl are mixed  ? (AIPMT 2015)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

At 100C the Kw of water is 55 times its value at 25C. What will be the pH of neutral solution? (log 55 = 1.74) (NEET 2013)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Accumulation  of  lactic  acid  (HC3H5O3),  a  monobasic acid in tissues leads to pain and a feeling of fatigue. In a 0.10  M  aqueous  solution,  lactic  acid  is  3.7% dissociated. The value of dissociation constant…

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