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HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

How many milliliters of 0.250 M NH4Cl would have to be  added  to  450  mL  of  0.350  M  KOH  in  order  to produce a buffer solution with a pH of 9.10? (Kb(NH3) = 1.8 × 10–5)

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Which  pair  of  reagents,  mixed  in  the  appropriate proportion, could make a buffer in pH 3-4 range ?

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

A buffer is prepared by adding 0.30 mol CH3COONa to 2.0  L  of  a  0.10  M  CH3COOH  solution.  Calculate the eq K /c (x y) eq K c/(xy) 1/(x y) x y 1 x y eq K /c x y eq K /xyc pH  after  0.030  mol  HCl  are …

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The pH of 10–5 M HCl solution if 1 ml of it is diluted to 1000 ml is :

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

When one drop of a concentrated HCl is added to 1 L of pure water at 25ºC, the pH drops suddenly from 7 to 4. When the second drop of the same acid is added, the pH of the solution further drops to about

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

A student dissolved 0.100 mol of an unknown monoprotic acid, HA, in sufficient water to make 1.00 L of solution. She measured the pH of the solution as pH = 2.60. Of the following, the acid HA is

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

For  a  “c  molar”  concentrated  solution  of  a  weak electrolyte AxBy, the degree of dissociation is given as (a) (b) (c) (d)

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

What is the equilibrium [OH–] in 0.1413 M H2CO3 ? H CO H O H O HCO (Ka = 4.30 ×10–7)

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

A mixture of weak acid is 0.1 M in HCOOH a K 1.8 10 x and 0.1 M in HOCN a K 3.1 10 x Hence, [H O ]  is

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The equilibrium constant for this reaction is approximately 10–3. HPO (aq.) HCO (aq.) H PO (aq.) CO (aq.) Which is the strongest conjugate base in this reaction? (a) HPO (aq.) (b) HCO (aq.) (c) H PO (aq.) (d…

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Consider  the  following  reaction  which  proceeds predominantly forward HSO NH NH SO From the information given it is clear that (a) HSOis a stronger acid than NH.

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The pH of the solution containing 50 mL each of 0.10 M sodium acetate and 0.01 M acetic acid is [Given pKa of CH3COOH = 4.57] (NEET 2022)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Equimolar  solutions  of  the  following  substances  were prepared separately. Which one of these will record the highest pH value? (AIPMT 2012)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

pH of a saturated solution of Ba(OH)2 is 12. The value of solubility product (Ksp) of Ba(OH)2 is (AIPMT 2012, 2010)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

A buffer solution is prepared in which the concentration of NH3 is 0.30 M and the concentration of NH is 0.20 M. If the equilibrium constant, Kb for NH3 equal 1.8 x 105, what is the pH of this solution? (log 2.7 = 0.4…

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Which  of  the  following  is  least  likely  to  behave  as Lewis’s base? (AIPMT 2011)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

In  a  buffer  solution  containing  equal  concentration  of B–  and  HB,  the  Kb  for  B–  is  1010.  The  pH  of  buffer solution is (AIPMT 2010)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

What is [H+] in mol/L of a solution that is 0.20 M in CH3COONa  and  0.10  M  in  CH3COOH?  (Ka  for CH3COOH = 1.8 x 10-5) (AIPMT 2010)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Which one of the following molecular hydrides acts as a Lewis’s acid? (AIPMT 2010)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Equal volumes of three acid solutions of pH 3, 4 and 5 are  mixed  in  a  vessel.  What  will  be  the  H+  ion concentration in the mixture ?  (CBSE AIPMT 2008) (a) –4 1.11 10 M x (b) 3.7 10 M x (c) 3.7 10 M x (d) …

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Which of the following is correct? (CPMT 2008)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

The pH of 10–8 M HCl solution is (AFMC 2008)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Calculate the pOH of a solution at 25C that contains 1 x 1010 M of hydronium ions, i.e., H3O+. (AIPMT 2007)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

A weak acid, HA, has a K  of 1.00 × 10–5. If 0.100 mole of this acid is dissolved in 1L of water, the percentage of acid dissociated at equilibrium is closest to (CBSE AIPMT 2007)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryIonic equilibrium

Degree  of  dissociation  of  0.1  N is acid (K 1 10 ) x (CPMT 2006) (a) (b) (c) (d)

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