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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

At 90oC, pure water has H3O+ ion concentration of 10-6 mol/L. The Kw at 90oC is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The  hydrogen  ion  concentration  of  a  10–8  M  HCl  aq. solution at 298K (Kw = 10–14) is (a) 1.0 10 M x (b) 1.10 10 M x (c) 9.525 10 M x (d) 1.0 10 M x

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The concentration of water molecules in pure water at 298 K is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

For a pure water,

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

A monoprotic acid in 1.00 M solution is 0.01% ionized. The dissociation constant of this acid is (a) 1 10 x (b) 1 10 x (c) 1 10 x (d) 1 10 x

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

At infinite dilution, the percentage ionisation  for  both strong and weak electrolytes is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Concentration CN – in 0.1 M HCN is [Ka = 4 × 10 –10]

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

For  a  weak  acid  HA,  Ostwald’s  dilution  law  is represented by the equation (a) a c K 2 (b) a c K (c) a K c c (d) a c K

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The a K   of  an  acid  is 3.2 10 x .  The  degree  of dissociation of the acid at concentration of 0.2M is (a) 6.0 10 x (b) –2 1.26 10 x (c) –4 x (d) 0.04 10 x

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The conjugate acid of HPO4 2– is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Conjugate base of NH3 is (a) NH (b) NH (c) NH

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The correct order of acid strength is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Cl – is the conjugate base of

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The conjugate base of NH2 – is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

A weak acid, HA has a Ka of 1.00 10 x . If 0.100 mole of this acid is dissolved in 1 L of water, the percentage of acid dissociated at equilibrium is closest to

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

The correct order of acid strength is

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

The  solubility  of  CaCO3  is  7  mg/L.  Calculate  the solubility product of BaCO3 from this information and from  the  fact that  when  Na2CO3  is added slowly  to  a solution  containing  equimolar  concentration …

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

The solubility of AgCl is maximum in

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

The solubility of LiOH in a solution with pH = 8 is (Ksp = 1.8 × 10–12)

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Assertion (A): pH of HCl solution is less than that of acetic acid of the same concentration. Reason (R):  In  equimolar  solutions,  the  number  of titrable protons present in HCl in less than that present in acetic…

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Assertion: If HA and HB are two weak non-basic acids with Ka(HA)  < Kb(HB), then, the aqueous solution  of NaA will have higher pH than pH of aqueous solution of NaB of same concentration. Reason: Conjugate base of  a…

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Assertion: When aqueous, solution of CH3COOAg is diluted, then its degree of hydrolysis increases. Reason:  Silver  acetate  is  the  salt  of  weak  acid  and weak base; its degree of hydrolysis does not depend on th…

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Assertion: When aqueous, solution of CH3COONH4 is diluted, then its degree of hydrolysis increases. Reason:  Ammonium  acetate  is  the  salt  of  weak  acid and  weak  base;  its  degree  of  hydrolysis  does  not de…

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Assertion: Aqueous  solution of  ammonium  carbonate is basic. Reason: Acidic or Basic nature of a salt solution of a salt  of  weak  acid  and  weak  base  depends  on  Ka  and Kb of the acid and base forming it.

HARDMCQ SINGLENEET ChemistryPhysical ChemistryIonic equilibrium

Assertion: If a K  of HA is 10–3 and a K  of HB is 10 at 25ºC, pH of an aqueous solution of HB will be one unit greater than pH of equimolar solution of HA. Reason:  For  weak  acids,  both  concentration  and ionizat…

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