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MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Which one of the statements is incorrect for aluminium metals?

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Aluminium exhibits +3 oxidation state. As we move down the group, +1 oxidation state gets more stable. This is a consequence of

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Group 13 elements show +1 and +3 oxidation states. Relative stability of +3 oxidation state may be given as (a) Tl Ga Al B In + + + + + > > > > (b) B Al Ga In Tl + + + + + > > > > (c) Al Ga Tl In B + + + + + > > > > (…

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

The stability of +1 oxidation state increases in the se- quence:

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Ionisation enthalpy i ( H kJ mol ) - D for the elements of Group 13 follows the order

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Trimethylammonia is pyramidal whereas trisilylammonia is a planar molecule. Why ?

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Specify the coordination geometry around and hybrid- ization of N and B atoms in 1:1 complex of BF3 and NH3:

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Which of the following is a Lewis acid ?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

The correct arrangement of following acids of phosphorus in the increasing order of oxidation state of phosphorus is (Guj CET 2014)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Assertion: The electronic structure of O3 is Reason: The following structure is not allowed because the octet around O cannot be expanded.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Assertion: O3 has a fishy smell. Reason: It absorbs red part of the visible light.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Assertion: Although PF5, PCl5 and PBr5 are known, the pentahalides of nitrogen have not been observed. Reason: Phosphorous has a lower electronegativity than nitrogen.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Assertion: HNO3 is a stronger acid than HNO2. Reason: In HNO3 there are two nitrogen to oxygen bonds whereas in HNO2 there is only one.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

The shape of XeO2F2 molecule is:

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

The oxidation state of xenon atom in XeF4, HXeO and Na4XeO6 are respectively:

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

When F2 reacts with hot and conc. alkali, then following will be obtained: (i) OF2 (ii) O2 (iii) H2O (iv) NaF

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Dry Cl2 reacts with dry SO2 to form:

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Which of the following oxides of chlorine is obtained by passing dry chlorine over silver chlorate at 900C?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

HClO4 + P2O5 -> (A) + (B)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

When iodine is treated with a mixture of NaF, NaBr and NaCl in water, it gives

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Liquid I2 Cl6 has the structure (a)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

The property of halogens, that indicated incorrect is:

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

NH4Cl is preferred to NaCl for the preparation of HCl by the action of concentrated H2SO4 because

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

When H2S gas is passed into aqueous sulphur dioxide

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Na2SO3 on being heated with sulphur produces

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