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MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following are not state functins? (I) q + w (II) Q (III) w (IV) H – TS (2009)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The heat liberated when 1.89 g of benzoic acid is burnt in a bomb calorimeter at 25 °C increases the temperature of 18.94 kg of water by 0.632 °C. If the specific heat of water at 25 °C is 0.998 cal/g-deg, the value o…

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The following two reactions are known Fe₂O₃(s) + 3CO(g) → 2Fe(s) + 3CO₂(g); ∆H = –26.8 kJ FeO(s) + CO(g) → Fe(s) + CO₂(g); ∆H = – 16.5 kJ The value of ∆H for the following reaction Fe₂O₃(s) + CO(g) → 2FeO(s) + CO₂(g) …

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

From the following bond energies: H — H bond energy : 431.37 kJ mol–1 C == C bond energy : 606.10 kJ mol–1 C — C bond energy : 336.49 kJ mol–1 C — H bond energy : 410.50 kJ mol–1 Enthalpy for the reaction, will be (2009)

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which thermodynamic parameter is not a state function?

HARDINTEGERNEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

If one monoatomic gas is expanded adiabatically from 2L to 10L at 1 atm external pressure then the value of U (in atm L) is

HARDMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Bond dissociation energy of CH₄ is 360 kJ/mol and C₂H₆ is 620 kJ/mol. Then bond dissociation energy of C – C bond is

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Standard entropies of X2, Y₂ and XY₃ are 60, 40 and 50 J K–1 mol–1 respectively. For the reaction 1/2X2 + 3/2Y₂ ⇌ XY₃, ∆H = –30 kJ, to be at equilibrium, the temperature should be (2010)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The state of a thermodynamic system is represented by

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which is included in thermodynamic equilibrium from the following?

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For irreversible expansion of an ideal gas under isothermal condition, the correct option is (NEET 2021)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assume each reaction is carried out in an open container. For which reaction will H = E ? (CBSE AIPMT 2006) (a) H (g) Br (g) 2HBr(g) → (b) C(s) 2H O(g) 2H (g) CO (g) → (c) PCl (g) PCl (g) Cl (g) → (d) 2CO(g) O (g) 2CO…

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A reaction occurs spontaneously if (2005)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Identify the correct statement for change of Gibbs’ energy for a system system ( G ) at constant temperature and pressure. (2006)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. The standard free energy difference ( G ) is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamon…

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

If the bond energies of H–H, Br–Br, and H–Br are 433, 192 and 364 kJ mol–1 respectively, the H for the reaction 2(g) 2(g) (g) H Br 2HBr → is (2004)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The absolute enthalpy of neutralisation of the reaction: (g) (g) 2(aq) (l) MgO 2HCl MgCl H O → Will be (2005)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The enthalpy and entropy change for the reaction: 2(l) 2(g) (g) Br Cl 2BrCl → are 30 kJ mol–1 and 105JK–1 mol–1 respectively. The temperature at which the reaction will be in equilibrium is (2006)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The standard enthalpies of formation of HCl(g), H  (g) and  Cl₂(g)  are  –92.2,  217.7  and  121.4  kJ  mol-1 respectively. The bond dissociation energy of HCl is:

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

H for the reaction, C(graphite) 2H (g) CH (g) → at 298 K and 1 atm is – 17900 cal.  The E for the above conversion would be

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the reaction, 8 g 2 g 2 g l C H 5O 3CO 4H O → at constant temperature, H E is (2003)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The heat of formation of Fe O s is –824.2 kJ mol–1. ∆H for the reaction. 2Fe O s 4Fe s 3O g → is:

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

When 0.5 g of sulphur is burnt to SO₂ 4.6 kJ of heat is liberated. What is the enthalpy of formation of sulphurdioxide?

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

105. (∆U – ∆H) for the formation of NH₃ from N₂ and H₂ is :

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The molar heat capacity of water at constant pressure, C, is 75J K-1. When 1.0 kJ of heat is supplied to 100 g of water which is free to expand, the increase in temperature of water is. (2003)

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