Chemistry Question Bank

The reaction between N2 and H2 to form ammonia has Kc = 6 × 10–2 at the temperature 500°C. The numerical value of Kp for this reaction is

For the reaction H2(g) + I2(g) 2HI(g) at 721K the value of equilibrium constant (Kc) is 50. When the equilibrium concentration of both is 0.5M, the value of Kp under the same conditions will be

In which of the following equilibria, the value of Kp is less than Kc

For N2(g) + 3H2(g) 2NH3(g) + heat

Which one of the following information can be obtained on the basis of Le Chatelier principle ?

In which of the following, the forward reaction is favoured by use of high pressure ?

Consider the reaction PCl5 (g) PCl3 (g) + Cl2 (g) in a closed container at equilibrium. At a fixed temperature what will be the effect of adding more PCl5 on the equilibrium concentration of Cl2 (g) ?

The standard state Gibb’s free energy change for the isomerization reaction cis-2-pentene trans-2-pentene is –3.67 kJ mol–1 at 400 K. If more trans-2-pentene is added to the reaction vessel

For a reversible reaction : A + B C dx dt = 2.0 × 103 L mol–1 s–1 [A] [B] – 1.0 × 102 s–1 [C] where x is the amount of ‘A’ dissociated. The value of equilibrium constant (Keq) is :

A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. Some of the CO2 is converted to CO on addition of graphite. If the total pressure at equilibrium is 0.8 atm, the value of K is :

The free energy of formation of NO is 78 kJ mol–1 at the temperature of an automobile engine (1000 K). What is the equilibrium constant for this reaction at 1000 K ? N (g) O (g) NO(g)

For the reaction, A B + C, at equilibrium, the concentration of A is 1 × 10–3 M, B is 0.15 and C is 0.05 M. The Gº for the hydrolysis of A at 27ºC will be :

The volume of the reaction vessel containing an equilibrium mixture is increased, while holding the temperature constant for the following reaction : SO2Cl2(g) SO2(g) + Cl2(g) When equilibrium is re-established, which…

In the equilibrium reaction AgCl(s) + 2NH3(g) 3 2 Ag(NH ) (aq) Cl (aq), an increase in the concentration of Cl –(aq) causes

Densities of diamond and graphite are 3.5 and 2.3 g/mL respectively. Increase of pressure on the equilibrium C (diamond) C (graphite)

In which of the following gaseous reaction, the value of Kp will be equal to Kc

Calculate c K for the reversible process given below if p K 167 and T = 800ºC CaCO (s) CaO(s) CO (g)

For which one of the following reactions p c K K ? (a) PCl PCl Cl (b) N O 2NO (c) N 3H 2NH (d) 2SO 2SO O

Kc for the reaction N2 (g) + O2 (g) 2 NO (g) at 300 K is 4.0 × 10–6. Kp for the above reaction will be (R = 2 cal mol–1 K–1)

For reaction PCl3 (g) + Cl2 (g) PCl5 (g), the value of Kc at 250ºC is 26. The value of Kp at this temperature will be :

If Kp for a reaction A (g) + 2 B (g) 3 C (g) + D (g) is 0.05 atm at 1000 K. Its Kc in terms of R will be

When a liquid in equilibrium with its vapour is heated

Consider the following equilibria for gases : H2S(g) H2S(aq) + 4.6 Kcal ; SO2(g) SO2(aq) + 8.6 Kcal. Assuming the randomness factor to be about the same for each, which of the gases will have the lower solubility in…

Which of the following equilibria will shift to right side on increasing the temperature ? (PMT 2000)

The equilibrium SO2Cl2 (g) SO2 (g) + Cl2 (g) is attained at 25ºC in a closed container and an inert gas, helium is introduced. Which of the following statement is correct ? (PMT 2000)