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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Vapour pressure of a pure liquid X is 2 atm at 300 K. It is lowered to 1 atm on dissolving 1g of Y in 20g of liquid X. If molar mass of X is 200, what is the molar mass of Y?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Vapour pressure of dilute aqueous solution of glucose is 750 mm of Hg at 373 K. The mole fraction of solute is (vapour pressure of pure water is 760 mm of Hg) SOLUTIONS

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Of the following 0.10 m aqueous solutions, which one will exhibit the largest freezing point depression? (AIPMT 2014)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The vapour pressures of two liquids A and B in their pure states are in the ratio of 1: 2. A binary solution of A and B contains A and B in the mole proportion of 1: 2. The mole fraction of A in the vapour phase of th…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

To observe an elevation in boiling point of 0.050C, the amount of a solute (molecular weight = 100) to be added to 100 g of water (Kb =0.5) is (WB JEE 2014)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

An ideal solution is formed when its constituents

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The empirical formula of a non-electrolyte is CH₂O. A solution containing 3 g of the compound exerts the same osmotic pressure as that of 0.05 M glucose solution. The molecular formula of the compound is (KCET 2011)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Addition of a non-volatile solute causes lowering in vapour pressure of a solvent from 0.8 atm to 0.2 atm. What is the mole fraction of solvent?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The mixture that forms maximum boiling azeotrope is: (NEET 2019)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

An aqueous solution containing 1g of urea boils at 100.25ºC. The aqueous solution containing 3g of glucose in the same volume will boil at

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Which of the following graphs represent the behavior of ideal binary liquid mixture?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

An aqueous solution is 1.0 molal in KI. Which change will cause the vapour pressure of the solution to increase? (AIPMT 2010)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

A solution of sucrose (molar mass = 342g mol -l) has been prepared by dissolving 68.5g of sucrose in 1000g of water. The freezing point of the solution obtained will be (Kf for water = 1.86 K Kg mol-l) (AFMC 2010) (a)…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

If the elevation in boiling point of a solution of 10 g of solute (molecular weight = 100) in 100 g of water is b T , the ebulliscopic constant of water is (Manipal 2010)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Henry’s law constant of oxygen is 1.4 × 10–3 mol L–1. atm–1 at 298 K. How much of oxygen is dissolved in 100 mL at 298 K when the partial pressure of oxygen is 0.5 atm? (Kerala CEE)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The vapour pressure of benzene at a certain temperature is 640 mm of Hg. A non-volatile electrolyte solute weighing 2.175 g is added to 30.08 g of benzene. If the vapour pressure of the solution is 600 mm of Hg, what …

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Vapour pressure of pure ‘A’ is 70 mm of Hg at 25ºC. It forms and ideal solution with ‘B’ in which mole fraction of A is 0.8. If the vapour pressure of the solution is 84 mm of Hg at 25ºC, the vapour pressure of pure ‘…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Given below are few mixtures formed by mixing two components. Which of the following binary mixtures will have same composition in liquid and vapour phase? (i) Ethanol + Chloroform (ii) Nitric acid + Water (iii) Benze…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

100 ml of a liquid A was mixed with 25 ml of a liquid B to give a non-ideal solution of A-B mixture. The volume of this mixture would be

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

An azeotropic solution of two liquids has boiling point lower than either of them when it

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Which one is a colligative property?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The vapour pressure of pure solvent is 0.8 mm of Hg at a particular temperature. On addition of a non-volatile solute ‘A’ the vapour pressure of solution becomes 0.6 mm of Hg. The mole fraction of component ‘A’ is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The vapour pressure of benzene at a certain temp. is 640 mm Hg . A non-volatile-non-electrolyte solid weighing 2.175g is added to 39.0 g of benzene. The vapour pressure of the solution is 600 mm Hg. What is the molecu…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Relative lowering of vapour pressure of a dilute solution is 0.2 what is the mole fraction of the non- volatile solute?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The boiling point of water is 1000C. What will be the boiling point of an aqueous solution containing 0.6 g of urea (molar mass = 60) in 100 of water? b k for water 0.52 K / m (RPMT 2010) (a) o 100.052 C (b) o 101.052…

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