MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutionsPrevious Year Questions

The empirical formula of a non-electrolyte is CH₂O. A solution containing 3 g of the compound exerts the same osmotic pressure as that of 0.05 M glucose solution. The molecular formula of the compound is (KCET 2011)

A.CH₂O
B.C₂H₄O₂✓ Correct
C.C₄H₈O₄
D.C₃H₆O₃
Explanation

For isotonic solution, 1 2 So, 1 2 1 2 w w M M Mass of 0.05 M glucose 0.05 180 9g x 6 12 6 Molecularmassof glucose C H O 180 1 1 3 9 M 60g M 180 >> molecular weight 60 n 2 empiricalformula weight 30 The molecular formula of the compound 2 2 4 2 2 CH O C H O

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