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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Assume each reaction is carried out in an open container. For which reaction will H = E ? (CBSE AIPMT 2006) (a) H (g) Br (g) 2HBr(g) → (b) C(s) 2H O(g) 2H (g) CO (g) → (c) PCl (g) PCl (g) Cl (g) → (d) 2CO(g) O (g) 2CO…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following are not state functins? (I) q + w (II) Q (III) w (IV) H – TS (2009)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. The standard free energy difference ( G ) is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamon…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The absolute enthalpy of neutralisation of the reaction: (g) (g) 2(aq) (l) MgO 2HCl MgCl H O → Will be (2005)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The heat of formation of Fe O s is –824.2 kJ mol–1. ∆H for the reaction. 2Fe O s 4Fe s 3O g → is:

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

105. (∆U – ∆H) for the formation of NH₃ from N₂ and H₂ is :

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

H for the reaction, C(graphite) 2H (g) CH (g) → at 298 K and 1 atm is – 17900 cal.  The E for the above conversion would be

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The standard enthalpies of formation of HCl(g), H  (g) and  Cl₂(g)  are  –92.2,  217.7  and  121.4  kJ  mol-1 respectively. The bond dissociation energy of HCl is:

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

When 0.5 g of sulphur is burnt to SO₂ 4.6 kJ of heat is liberated. What is the enthalpy of formation of sulphurdioxide?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The following data is known about the melting of a compound AB. ∆H = 9.2 kJ mol–1. ∆S = 0.008 kJ K–1mol–1. Its melting point is :

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. If the standard free energy difference is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamond a…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the reaction, 2H O g 2H g O g → ∆H = 571.6 KJ fH of water is :

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The enthalpy of vaporisation of a compound AB at its boiling point (127°C) is 6.4 kJ mol-1. Its entropy of vaporization is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

∆H for the reaction, SO g O g SO g ∆H = –98.3 kJ If the enthalpy of formation of SO₃(g) is –395.4 kJ then the enthalpy of formation of SO₂(g) is :

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the reaction, 8 g 2 g 2 g l C H 5O 3CO 4H O → at constant temperature, H E is (2003)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

In which of the following cases, the reaction is spontaneous at all temperatures ?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Cell reaction is spontaneous when (a) G is negative (b) G is positive (c) red G is positive (d) red G is negative

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Enthalpy change for the reaction, 4H(g)  → 2H₂(g) is – 869.5 kJ. The dissociation energy of H–H bond is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

2 moles of ideal gas at 27°C temperature is expanded reversibly from 2 lit. to 20 lit. find entropy change. (R = 2 cal/mol K)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Pick out the wrong statement

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the gas phase reaction, PCl g PCl g Cl g Which of the following conditions are correct?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

G is the net energy available to do useful work and is a measure of free energy. If a reaction has positive enthalpy change and positive entropy change, under what conditions will the reaction be spontaneous?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following reactions define o f G ? (a) diamond C O g CO g → (b) H g F g HF g → (c) H P O H O 2H PO → (d) SO g O g SO g →

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

When one mole of an ideal gas is compressed to half of its initial volume and simultaneously heated to twice its initial temperature, the change in entropy of gas (∆S) is :

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryThermodynamics and Thermochemistry

One mole of an ideal diatomic gas (Cv = 5 cal) was transformed from initial 25°C and 1 L to the state when temperature is 100°C and volume 10 L. The entropy change of the process can be expressed as (R = 2 calories/mo…

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