19,000+ solved questions for JEE Advanced, JEE Mains, NEET & IChO — with answers and expert explanations.
Assume each reaction is carried out in an open container. For which reaction will H = E ? (CBSE AIPMT 2006) (a) H (g) Br (g) 2HBr(g) → (b) C(s) 2H O(g) 2H (g) CO (g) → (c) PCl (g) PCl (g) Cl (g) → (d) 2CO(g) O (g) 2CO…
Which of the following are not state functins? (I) q + w (II) Q (III) w (IV) H – TS (2009)
The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. The standard free energy difference ( G ) is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamon…
The absolute enthalpy of neutralisation of the reaction: (g) (g) 2(aq) (l) MgO 2HCl MgCl H O → Will be (2005)
The heat of formation of Fe O s is –824.2 kJ mol–1. ∆H for the reaction. 2Fe O s 4Fe s 3O g → is:
105. (∆U – ∆H) for the formation of NH₃ from N₂ and H₂ is :
H for the reaction, C(graphite) 2H (g) CH (g) → at 298 K and 1 atm is – 17900 cal. The E for the above conversion would be
The standard enthalpies of formation of HCl(g), H (g) and Cl₂(g) are –92.2, 217.7 and 121.4 kJ mol-1 respectively. The bond dissociation energy of HCl is:
When 0.5 g of sulphur is burnt to SO₂ 4.6 kJ of heat is liberated. What is the enthalpy of formation of sulphurdioxide?
The following data is known about the melting of a compound AB. ∆H = 9.2 kJ mol–1. ∆S = 0.008 kJ K–1mol–1. Its melting point is :
The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. If the standard free energy difference is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamond a…
For the reaction, 2H O g 2H g O g → ∆H = 571.6 KJ fH of water is :
The enthalpy of vaporisation of a compound AB at its boiling point (127°C) is 6.4 kJ mol-1. Its entropy of vaporization is
∆H for the reaction, SO g O g SO g ∆H = –98.3 kJ If the enthalpy of formation of SO₃(g) is –395.4 kJ then the enthalpy of formation of SO₂(g) is :
For the reaction, 8 g 2 g 2 g l C H 5O 3CO 4H O → at constant temperature, H E is (2003)
In which of the following cases, the reaction is spontaneous at all temperatures ?
Cell reaction is spontaneous when (a) G is negative (b) G is positive (c) red G is positive (d) red G is negative
Enthalpy change for the reaction, 4H(g) → 2H₂(g) is – 869.5 kJ. The dissociation energy of H–H bond is
2 moles of ideal gas at 27°C temperature is expanded reversibly from 2 lit. to 20 lit. find entropy change. (R = 2 cal/mol K)
Pick out the wrong statement
For the gas phase reaction, PCl g PCl g Cl g Which of the following conditions are correct?
G is the net energy available to do useful work and is a measure of free energy. If a reaction has positive enthalpy change and positive entropy change, under what conditions will the reaction be spontaneous?
Which of the following reactions define o f G ? (a) diamond C O g CO g → (b) H g F g HF g → (c) H P O H O 2H PO → (d) SO g O g SO g →
When one mole of an ideal gas is compressed to half of its initial volume and simultaneously heated to twice its initial temperature, the change in entropy of gas (∆S) is :
One mole of an ideal diatomic gas (Cv = 5 cal) was transformed from initial 25°C and 1 L to the state when temperature is 100°C and volume 10 L. The entropy change of the process can be expressed as (R = 2 calories/mo…