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HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

A hydrocarbon A on chlorination gives B which on heating with alcoholic potassium hydroxide changes into another hydrocarbon C. The latter decolourises Baeyer's reagent and on ozonolysis forms formaldehyde only. A is

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

CH CH CH

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

In the presence of platinum catalyst, hydrocarbon A adds hydrogen to form n-hexane. When hydrogen bromide is added to A instead of hydrogen, only a single bromo compound Is formed. Which of the following is A? (a) CH …

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

When 3, 3-dimethyl 2-butanol is heated with H₂SO₄, the major product obtained is

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

When hydrochloric acid gas is treated with propene in presence of benzoyl peroxide, it gives.

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

The reagent is Reagent R CH CCl R R C C R →

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

Consider the following statements : A hydrocarbon of molecular formula C₅H₁₀ is a I. monosubstituted alkene II. disubstituted alkene III. trisubstituted alkene Which of the following statement(s) is(are) correct?

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

Which one of the following reactions is expected to readily give a hydrocarbon product in good yields? (a) Electrolytic RCOOK oxidation → (b) Br₂ RCOO Ag → (c) Br₂ RCOO Ag →

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

In the given reactions : Br Na,ether Na,ether (i)CH Br X Y Z hv Br NaOH NaOH (ii)CH COOH X Y Z CaO hv → → → → → → Identify X, Y and Z. X Y Z

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

Match the column I with column II and mark the appropriate choice. Column I Column II (A) n-butane 2-methylpropane (i) Free radical substitution (B) hv CH Cl CH Cl → (ii) Wurtz reaction (C) RCOONa + soda lime RH (iii)…

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

Assertion: Alkyl benzene is not prepared in good yield by Friedel-Craft’s alkylation of benzene. Reason: Alkyl halides are less reactive than acyl halides.

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

Which of the following statements is true ?

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

Assertion: Friedel-Craft’s reaction is used to introduce an alkyl or acyl group in the benzene nucleus. Reason: Benzene is a solvent for Friedel-Craft’s alkylation of bromobenzene.

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

Assertion: Rates of nitration of benzene and hexadeuterobenzene are different. Reason: The C—H bond is stronger than the C—D bond.

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

Select the true statement about benzene amongst the following

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

Product The main product is (a) (b) (c) (d)

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

The compound X in the reaction, (a) (b) (c) (d)

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

Among the following, the aromatic comopound is: (a) (b) (c) (d)

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

Acetylenic hydrogens are acidic because

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

CH CH C CH

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

CH CH CH CH

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

CH C C CH

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

Which is the most suitable reagent among the following to distinguish compound (3) from rest of the

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

The product A, is (a) (b) (c) (d)

HARDMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryHydrocarbons

Assertion: Alkynes are more reactive towards nucleophilic addition reaction as compared to alkenes. Reason: Alkynes contain two pi bonds, while alkenes have only one bond.

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