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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Which of the following reactions define o f G ? (a) diamond C O g CO g → (b) H g F g HF g → (c) H P O H O 2H PO → (d) SO g O g SO g →

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

H and E  for the reaction, Fe O s 3H g 2Fe s H O l → at constant temperature are related as (a) H E (b) H E RT (c) H E RT (d) H E 3RT

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The following data is known about the melting of a compound AB. ∆H = 9.2 kJ mol–1. ∆S = 0.008 kJ K–1mol–1. Its melting point is :

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. If the standard free energy difference is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamond a…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

When 0.5 g of sulphur is burnt to SO₂ 4.6 kJ of heat is liberated. What is the enthalpy of formation of sulphurdioxide?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The heat of formation of Fe O s is –824.2 kJ mol–1. ∆H for the reaction. 2Fe O s 4Fe s 3O g → is:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Two solutions A and B are separated by a semi- permeable membrane. As a result of osmosis, the level of solution A is found to rise. It implies that

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Which of the following pairs of solutions is isotonic?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

What would happen if a thin slice of sugar beet is placed in a concentrated solution of NaCl?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Which of the following colligative properties can provide molar mass of proteins (or polymers of colloids) with greater precision?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

A solution of urea (mol. mass 56 g mol–1) boils at 100.18ºC at the atmospheric pressure. If Kf and Kb for water are 1.86 and 0.512 K kg mol–1 respectively, the above solution will freeze at

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Which statement is incorrect about osmotic pressure (), volume (V) and temperature (T)?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The empirical formula of a non-electrolyte is CH₂O. A solution containing 6g/L of the compound exerts the same osmotic pressure as that of 0.05 M glucose solution. The molecular formula of the compound is SOLUTIONS

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The freezing point of 1 molal Glucose solution in water is ( 1.86 H O f K K kg mol )

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

0.052 100.052 6 / 60 x x x x b b b b b o b T T T T T T C 102. An aqueous solution of Glucose freezes at –0.186 °C. Given that 0.512 H O b K K kg mol and 1.86 H O f K K kg mol , the elevation in boiling point of this s…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Kf for water is 1.86 K kg mol–1. If your automobile radiator holds 1.0 kg of water, how many grams of ethylene glycol (C₂H₆O₂) must you add to get the freezing point of the solution lowered to –2.8ºC?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

If 15 gm of a solute in 100 gm of water makes a solution that freezes at –1.0ºC, then 30 gm of the same solute in 100 gm of water will make a solution that freezes at

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The molar freezing point constant for water is 1.86º C/m. If 342g of cane sugar (C₁₂H₂₂O₁₁) is dissolved in 1000 g of water, the solution will freeze at

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

An aqueous solution of a non-electrolyte solute boils at 100.52ºC. The freezing point of the solution will be (Kf = 1.86K Kg mol-1, Kb = 0.52 K kg mol-1)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Ethylene glycol is used as an antifreeze in a cold climate. Mass of ethylene glycol which should be added to 4 kg of water to prevent it from freezing at – 6ºC will be (Kf for water = 1.86 K kg mol–1. and molar mass o…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Solutions A, B, C and D are respectively 0.1M glucose, 0.05 M NaCl, 0.05 M BaCl₂ and 0.1 M AlCl₃. Which one of the following pairs is isotonic?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Pure benzene freezes at 5.45ºC at a certain place but a 0.374m solution of tetrachloroethane in benzene freezes at 3.55ºC. The Kf for benzene is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The freezing point of a 0.05 molal solution of a non- electrolyte in water is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Depression of freezing point for …(i)… is directly proportional to …(ii)… Here, (i) and (ii) refer to

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Sprinkling of salt helps in clearing the snow covered roads in hills. The phenomenon involved in the process is

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