MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and ThermochemistryRelationship Between ΔH and ΔU
The heat of formation of Fe O s is –824.2 kJ mol–1. ∆H for the reaction. 2Fe O s 4Fe s 3O g → is:
A.–412.1 kJ
B.–1648.4 kJ
C.–3296.8 kJ✓ Correct
D.1648.4 kJ
Explanation
f H H 2 ( 824.2) 2 [ H 1648] x x 100. The H for the reaction, 2 3 4S s 6O g 4SO g → is –1583.2 kJ. Standard enthalpy of formation of sulphur trioxide is : (a) –3166.4 kJ (b) 3166.4 kJ (c) –395.8 kJ (d) 395.8 kJ H 1583.2 Hg 395.8kJ 4 4 101. Calculate the heat of formation of PCl₅(s) from the following data : 2P(s) + 3Cl₂ (g) → 2PCl₃(l) ∆H = –151.8 kcal PCl₃(l) + Cl₂(g) → PCl₅(s) ∆H = –32.8 kcal (a) –108.7 kcal (b) 108.7 kcal (c) –184.6 kcal (d) 184.6 kcal 2 s 5 s 5 P Cl PCl 2 → s 2 g 3 l 3 l 2 g 5 s s 2 g 5 s 3 1
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