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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

A reaction has ∆H = – 33 kJ and ∆S = +58 J/K. This reaction would be :

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For the gas phase reaction, PCl g PCl g Cl g Which of the following conditions are correct?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The enthalpy of vaporisation of a compound AB at its boiling point (127°C) is 6.4 kJ mol-1. Its entropy of vaporization is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Identify the correct statement for change of Gibbs’ energy for a system system ( G ) at constant temperature and pressure. (2006)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The bond dissociation energies of X2, Y₂ and XY are in the ratio of 1 : 0.5 : 1. ∆H for the formation of XY is – 200 kJ mol–1. The bond dissociation energy of X2 will be (NEET 2018)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Which one among the following is the correct option for right relationship between CP and CV for one mole of ideal gas? (NEET 2021)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which of the following expressions regarding entropy is not correct? (a) system q S T (b) system total surrounding S S S (c) final initial S S S (d) total system surrounding S S S

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Read the following statements regarding spontaneity of a process and mark the appropriate choice. (i)   When enthalpy factor is absent then randomness factor decides spontaneity of a process. (ii) When randomness fact…

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

One mole of an ideal gas expands reversibly and adiabatically from a temperature of 27°C. If the work done during the process is 3 kJ, then final temperature of the gas is:(CV = 20 J/K)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Which one of the following has  S  greater than zero? (a) CaO s CO g CaCO s (b) NaCl aq NaCl s (c) NaNO s Na aq NO aq (d) N g 3H g 2NH g

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

G T S  when H

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Calculate the work done when 1 mole of an ideal gas is compressed reversibly form 1 bar to 4 bar at a constant temperature of 300 K.

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The work done during the expansion of a gas from a volume of 4dm3 to 6 dm3 against a constant external pressure of 3 atm is

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Molar heat capacity of water in equilibrium with ice at constant pressure is

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

1 mole of NH₃ gas at 27°C is expanded in reversible adiabatic condition to make volume 8 times (γ = 1.33). Final temperature and work done by the gas respectively are:

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

16g of oxygen gas expands isothermally and reversibly at 300 K from 10 dm3 to 100 dm3. The work done is (in J)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

G H T S when H S Hence, Correct option is c

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A given mass of gas expands from state A to state B by three paths 1, 2, and 3 as shown in the figure: If w ,w  and w  respectively, be the work done by the gas along three paths, then (a) w w w (b) w w w

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

One mole of an ideal gas is initially at 0°C and 1 atm pressure. If it absorbs 1000 cal heat during a reversible isothermal expansion, what will be its final volume?

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The pressure of a gas is 100 kPa. If it is compressed from 1m3 to 10 dm3, find the work done.

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

An ideal gas expands in volume from 1 × 10–3 to 1 × 10–2 m3 at 300 K against a constant pressure 1 × 105 Nm–2. The work done is

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The maximum work obtained by an isothermal reversible expansion of 1 mole of an ideal gas at 27°C from 2.24 to 22.4 L is (R = 2 cal)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Calculate the work done when 1 mol of an ideal gas is compressed reversibly from 1 bar to 4 bar at a constant temperature of 300 K

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

An ideal gas is taken around the cycle ABCA as shown in P-V diagram The net work done by the gas during the cycle is equal to:

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Considering entropy (s) as a thermodynamic parameter, the criterion for the spontaneity of any process is (a) system surroundings S S (b) system surroundings S S (c) system S 0 only (d) surroundings S 0only

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