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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Two moles of Helium gas undergo a reversible cyclic process as shown in figure. Assuming gas to be ideal. What is the work done for the process C to D?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

E is always positive, when

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

An ideal gas is taken around the cycle ABCA as shown in P-V diagram The net work done by the gas during the cycle is equal to:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

An ideal gas receives 10 J of heat in a reversible isothermal expansion. Then the work done by the gas:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

A given mass of gas expands from state A to state B by three paths 1, 2, and 3 as shown in the figure: If w ,w  and w  respectively, be the work done by the gas along three paths, then (a) w w w (b) w w w

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

One mole of an ideal gas is initially at 0°C and 1 atm pressure. If it absorbs 1000 cal heat during a reversible isothermal expansion, what will be its final volume?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Calculate the work done when 1 mol of an ideal gas is compressed reversibly from 1 bar to 4 bar at a constant temperature of 300 K

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

16g of oxygen gas expands isothermally and reversibly at 300 K from 10 dm3 to 100 dm3. The work done is (in J)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For a given reaction, ∆H = 35.5 kJ mol–1 and ∆S = 83.6 J K–1 mol–1. The reaction is spontaneous at (Assume that ∆H and ∆S do not vary with temperature.) (NEET 2017)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

In which case change in entropy is negative? (NEET 2019)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Which one of the following has  S  greater than zero? (a) CaO s CO g CaCO s (b) NaCl aq NaCl s (c) NaNO s Na aq NO aq (d) N g 3H g 2NH g

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Which of the following expressions regarding entropy is not correct? (a) system q S T (b) system total surrounding S S S (c) final initial S S S (d) total system surrounding S S S

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

G T S  when H

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

G H T S when H S Hence, Correct option is c

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Unit of entropy is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

In which case change in entropy is negative?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For the reaction, X2O₄(l) → 2XO₂(g) ∆U = 2.1 kcal, ∆S = 20 cal K–1 at 300 K Hence, ∆G is (2014)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

When 5 litres of a gas mixture of methane and propane is perfectly combusted at 0°C and 1 atmosphere, 16 litres of oxygen at the same temperature and pressure is consumed. The amount of heat released from this combust…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The heat of combustion of carbon to CO₂ is –393.5 kJ/mol. The heat released upon formation of 35.2 g of CO₂ from carbon and oxygen gas is (2015)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

One mole of an ideal gas expands reversibly and adiabatically from a temperature of 27°C. If the work done during the process is 3 kJ, then final temperature of the gas is:(CV = 20 J/K)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

According to the first law of thermodynamics, U q w . In special cases the statement can be expressed in different ways. Which of the following is not a correct expression?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The enthalpy of vaporisation of a compound AB at its boiling point (127°C) is 6.4 kJ mol-1. Its entropy of vaporization is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For a sample of perfect gas when its pressure is changed isothermally from pi to pf, the entropy change is given by. (NEET-II 2016)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For the reaction, 2Cl(g) → Cl₂(g), the correct option is (NEET 2020)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The statement “The change of enthalpy of a chemical reaction is same whether the reaction takes place in one or several steps” is

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