Chemistry Question Bank

In the equilibrium reaction AgCl(s) + 2NH3(g) 3 2 Ag(NH ) (aq) Cl (aq), an increase in the concentration of Cl –(aq) causes

The volume of the reaction vessel containing an equilibrium mixture is increased, while holding the temperature constant for the following reaction : SO2Cl2(g) SO2(g) + Cl2(g) When equilibrium is re-established, which…

For the reaction, A B + C, at equilibrium, the concentration of A is 1 × 10–3 M, B is 0.15 and C is 0.05 M. The Gº for the hydrolysis of A at 27ºC will be :

The free energy of formation of NO is 78 kJ mol–1 at the temperature of an automobile engine (1000 K). What is the equilibrium constant for this reaction at 1000 K ? N (g) O (g) NO(g)

A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. Some of the CO2 is converted to CO on addition of graphite. If the total pressure at equilibrium is 0.8 atm, the value of K is :

For a reversible reaction : A + B C dx dt = 2.0 × 103 L mol–1 s–1 [A] [B] – 1.0 × 102 s–1 [C] where x is the amount of ‘A’ dissociated. The value of equilibrium constant (Keq) is :

The standard state Gibb’s free energy change for the isomerization reaction cis-2-pentene trans-2-pentene is –3.67 kJ mol–1 at 400 K. If more trans-2-pentene is added to the reaction vessel

Consider the reaction PCl5 (g) PCl3 (g) + Cl2 (g) in a closed container at equilibrium. At a fixed temperature what will be the effect of adding more PCl5 on the equilibrium concentration of Cl2 (g) ?

In which of the following, the forward reaction is favoured by use of high pressure ?

Which one of the following information can be obtained on the basis of Le Chatelier principle ?

According the Le-Chatelier’s principle, adding heat to a solid and liquid in equilibrium will cause the

For the gas phase reaction 2 NO N2 + O2, H = – 43.5 Kcal mol–1which one of the statement below is true for N2 (g) + O2 (g) 2 NO (g)

Change in volume of the system does not alter the number of moles in which of the following equilibrium

In which of the following system, doubling the volume of the container cause a shift to the right

The exothermic formation of ClF3 is represented by the equation Cl2(g) + 3F2(g) 2ClF3(g); H = – 329 kJ Which of the following will increase the quantity of ClF3 in an equilibrium mixture of Cl2, F2 and ClF3

The effect of increasing the pressure on the equilibrium 2A(g) + 3B(g) 3A(g) + 2B(g) is

Following gaseous reaction is undergoing in a vessel C2H4 + H2 C2H6; H = – 32.7 Kcal Which will increase the equilibrium concentration of C2H6

In the reaction A(g) + 2B(g) C(g) + Q kJ, greater product will be obtained or the forward reaction is favoured by

According to Le-Chatelier principle, if heat is given to solid-liquid system, then

The reaction A + B C + D +heat has reached equilibrium. The reaction may be made to proceed forward by

In the following reversible reaction 2SO2 + O2 2SO3 + Q Cal Most suitable condition for the higher production of SO3 is

Which of the following reactions proceed at low pressure

N2 + O2 2NO - Q cals In the above reaction which is the essential condition for the higher production of NO

The formation of SO3 takes place according to the following reaction, 2SO2 + O2 2SO3 ; H = – 45.2 Kcal The formation of SO3 is favoured by

In the reaction, A2(g) + 4 B2(g) 2AB4(g) + heat the formation of AB4will be favoured at