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MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

The standard state Gibb’s free energy change for the isomerization reaction cis-2-pentene trans-2-pentene is –3.67 kJ mol–1 at 400 K. If more trans-2-pentene is added to the reaction vessel

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

For a reversible reaction : A + B C dx dt = 2.0 × 103 L mol–1 s–1 [A] [B] – 1.0 × 102 s–1 [C] where x is the amount of ‘A’ dissociated. The value of equilibrium constant (Keq) is :

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. Some of the CO2 is converted to CO on addition of graphite. If the total pressure at equilibrium is 0.8 atm, the value of K is :

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

The free energy of formation of NO is 78 kJ mol–1 at the temperature of an automobile engine (1000 K). What is the equilibrium constant for this reaction at 1000 K ? N (g) O (g) NO(g)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

For the reaction, A B + C, at equilibrium, the concentration of A is 1 × 10–3 M, B is 0.15 and C is 0.05 M. The Gº for the hydrolysis of A at 27ºC will be :

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

The reaction (g) (g) (g) N O 2NO is endothermic. The forward reaction is (BHU 2003)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

The reaction quotient (Q) for the reaction N (g) 3H (g) 2NH (g) is given by [NH ] Q . [N ][H ] (CBSE Med. 2003) The reaction will proceed from right to left if

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

If N2 + 3H2 2 NH3 – K, then 2N2 + 6H2 4NH3 – ? (PMT 2002)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

When H2 and I2 are mixed and equilibrium is attained, then H I 2HI (PMT 2002)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

The equilibrium SO2Cl2 (g) SO2 (g) + Cl2 (g) is attained at 25ºC in a closed container and an inert gas, helium is introduced. Which of the following statement is correct ? (PMT 2000)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

Which of the following equilibria will shift to right side on increasing the temperature ? (PMT 2000)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

The volume of the reaction vessel containing an equilibrium mixture is increased, while holding the temperature constant for the following reaction : SO2Cl2(g) SO2(g) + Cl2(g) When equilibrium is re-established, which…

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

In the equilibrium reaction AgCl(s) + 2NH3(g) 3 2 Ag(NH ) (aq) Cl (aq), an increase in the concentration of Cl –(aq) causes

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

Densities of diamond and graphite are 3.5 and 2.3 g/mL respectively. Increase of pressure on the equilibrium C (diamond) C (graphite)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

When a liquid in equilibrium with its vapour is heated

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

Consider the following equilibria for gases : H2S(g) H2S(aq) + 4.6 Kcal ; SO2(g) SO2(aq) + 8.6 Kcal. Assuming the randomness factor to be about the same for each, which of the gases will have the lower solubility in…

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

3O2 (g) ⇌ 2O3(g) for the above reaction at 298 K, Kc is found to be 3.0 × 10-59. If the conc. of O2 at equilibrium is 0.040 M then concentration of O3 in M is. (NEET 2022)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

If the value of an equilibrium constant for a particular reaction is 1.6 × 1012, then at equilibrium the system will contain (AIPMT 2015) (a)mostly reactants

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

For the reversible reaction (AIPMT 2014) N (g) 3H (g) 2NH (g) Heat The equilibrium shifts in forward direction

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

For the reaction, C(s) + CO2(g) 2CO(g), p K 63atm at 1000 K. If at equilibrium CO CO p 10p , than the total pressure of the gases at equilibrium is (KERELA CEE 2011)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

In the reaction, AB (g) A(g) + B(g) at 30ºC, Kp for the dissociation equilibrium is 2.56 × 10–2 atm. If the total pressure at equilibrium is 1 atm, then the percentage dissociation of AB is (KERELA CEE 2011)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

The value of H for the reaction, (AIPMT 2011) X g 4Y g 2XY g is less than zero. Formation of XY4(g) will be favoured at

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

Consider the following gaseous equilibria with equilibrium constants K1 and K2 respectively. SO g O g SO g (KCET 2011) 2SO g 2SO g O g The equilibrium constants are related as (a) 2K K (b) K K (c) K K (d)…

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

For the reaction, N (g) O (g) 2NO(g) , the equilibrium constant is K1. The equilibrium constant is K2 for the reaction, 2NO(g) O (g) 2NO (g) . What is K for the reaction NO (g) N (g) O (g) (AIPMT 2011) (a) (K…

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryChemical Equilibrium

What is c K for the following equilibrium when equilibrium concentration of each substance is [SO ] 0.60 M, [O ] 0.82 M and [SO ] 1.90 M ? (VMMC 2010) 2SO (g) O (g) 2SO (g)

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