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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

If the enthalpy change for the transition of liquid water to steam is 30 kJ mol–1 at 27°C, the entropy change for the process would be (2011)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For the reaction, 2Cl(g) → Cl₂(g), the correct option is (NEET 2020)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

If the bond energies of H–H, Br–Br, and H–Br are 433, 192 and 364 kJ mol–1 respectively, the H for the reaction 2(g) 2(g) (g) H Br 2HBr → is (2004)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The molar heat capacity of water at constant pressure, C, is 75J K-1. When 1.0 kJ of heat is supplied to 100 g of water which is free to expand, the increase in temperature of water is. (2003)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. The standard free energy difference ( G ) is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamon…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

H for the reaction, C(graphite) 2H (g) CH (g) → at 298 K and 1 atm is – 17900 cal.  The E for the above conversion would be

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

105. (∆U – ∆H) for the formation of NH₃ from N₂ and H₂ is :

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The standard enthalpies of formation of HCl(g), H  (g) and  Cl₂(g)  are  –92.2,  217.7  and  121.4  kJ  mol-1 respectively. The bond dissociation energy of HCl is:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The absolute enthalpy of neutralisation of the reaction: (g) (g) 2(aq) (l) MgO 2HCl MgCl H O → Will be (2005)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

∆H for the reaction, SO g O g SO g ∆H = –98.3 kJ If the enthalpy of formation of SO₃(g) is –395.4 kJ then the enthalpy of formation of SO₂(g) is :

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

For the reaction, 2H O g 2H g O g → ∆H = 571.6 KJ fH of water is :

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

In a reaction, all reactant and products are liquid, then (a) H E (b) H E (c) H E

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Two moles of Helium gas undergo a reversible cyclic process as shown in figure. Assuming gas to be ideal. What is the work done for the process C to D?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

E is always positive, when

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

An ideal gas receives 10 J of heat in a reversible isothermal expansion. Then the work done by the gas:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The pressure of a gas is 100 kPa. If it is compressed from 1m3 to 10 dm3, find the work done.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

A given mass of gas expands from state A to state B by three paths 1, 2, and 3 as shown in the figure: If w ,w  and w  respectively, be the work done by the gas along three paths, then (a) w w w (b) w w w

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

One mole of an ideal gas is initially at 0°C and 1 atm pressure. If it absorbs 1000 cal heat during a reversible isothermal expansion, what will be its final volume?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

When 0.5 g of sulphur is burnt to SO₂ 4.6 kJ of heat is liberated. What is the enthalpy of formation of sulphurdioxide?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The work done during the expansion of a gas from a volume of 4dm3 to 6 dm3 against a constant external pressure of 3 atm is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Molar heat capacity of water in equilibrium with ice at constant pressure is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

1 mole of NH₃ gas at 27°C is expanded in reversible adiabatic condition to make volume 8 times (γ = 1.33). Final temperature and work done by the gas respectively are:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Which of the following expressions regarding entropy is not correct? (a) system q S T (b) system total surrounding S S S (c) final initial S S S (d) total system surrounding S S S

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Read the following statements regarding spontaneity of a process and mark the appropriate choice. (i)   When enthalpy factor is absent then randomness factor decides spontaneity of a process. (ii) When randomness fact…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The following data is known about the melting of a compound AB. ∆H = 9.2 kJ mol–1. ∆S = 0.008 kJ K–1mol–1. Its melting point is :

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